CYCLOPROPYLZINC BROMIDE SOLUTION 0.5M I& Chemical Properties

Density 

0.969 g/mL at 25 °C

Flash point:

-17 °C

storage temp. 

2-8°C

solubility 

Miscible with tetrahydrofuran.

form 

liquid

Sensitive 

Air Sensitive

Exposure limits

ACGIH: TWA 50 ppm; STEL 100 ppm (Skin)
OSHA: TWA 200 ppm(590 mg/m3)
NIOSH: IDLH 2000 ppm; TWA 200 ppm(590 mg/m3); STEL 250 ppm(735 mg/m3)

InChI

1S/C3H5.BrH.Zn/c1-2-3-1;;/h1H,2-3H2;1H;/q;;+1/p-1 || 1S/C3H5.BrH.Zn/c1-2-3-1;;/h1H,2-3H2;1H;/q;;+1/p-1

InChIKey

DUXRKEPSNWXJGV-UHFFFAOYSA-M || DUXRKEPSNWXJGV-UHFFFAOYSA-M

SMILES

Br[Zn]C1CC1 || Br[Zn]C1CC1

Safety Information

Hazard Codes 

F,Xi,Xn

Risk Statements 

11-15-19-36/37-40-36/37/38-14

Safety Statements 

16-26-33-43-36/37

RIDADR 

UN 3399 4.3/PG 2

WGK Germany 

3

HazardClass 

4.3

HS Code 

29319090

Storage Class

4.3 - Hazardous materials which set free flammable gases upon contact with water

Hazard Classifications

Acute Tox. 4 Oral
Carc. 2
Flam. Liq. 2
Skin Corr. 1B
STOT SE 3

CYCLOPROPYLZINC BROMIDE SOLUTION 0.5M I& Usage And Synthesis

Uses

Active nucleophile in Pd-catalyzed cross-coupling of heteroaryl halides.1

Uses

Cyclopropylzinc bromide acts as an active nucleophile in palladium-catalyzed cross-coupling of heteroaryl halides.

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