1,2-BIS((2R,5R)-2,5-DIMETHYLPHOSPHOLANO& Chemical Properties

Melting point:

116-122 °C

Boiling point:

484.0±28.0 °C(Predicted)

storage temp. 

under inert gas (nitrogen or Argon) at 2-8°C

form 

solid

color 

white

optical activity

[α]22/D -171°, c = 1 in chloroform

Sensitive 

Air Sensitive

InChI

1S/C18H28OP2/c1-13-9-10-14(2)20(13)17-7-5-6-8-18(17)21(19)15(3)11-12-16(21)4/h5-8,13-16H,9-12H2,1-4H3/t13-,14-,15-,16-/m1/s1

InChIKey

ORZVYNTUPREFTI-KLHDSHLOSA-N

SMILES

C[C@@H]1CC[C@@H](C)P1(C2=CC=CC=C2P3[C@H](C)CC[C@H]3C)=O

Safety Information

WGK Germany 

3

Storage Class

11 - Combustible Solids

1,2-BIS((2R,5R)-2,5-DIMETHYLPHOSPHOLANO& Usage And Synthesis

Uses

DuPhos and BPE Ligands: Highly Efficient Privileged Ligands

General Description

1,2-Bis[(2R,5R)-2,5-dimethylphospholano]benzene monooxide is a chiral ligand whose copper complexes are used extensively in many organic reactions such as addition to imines, nitroalkenes, and reduction of β,β-disubstituted vinyl sulfones.