Dichloro{(R)-(+)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole}[(2R)-(-)-1,1-bis(4-methoxyphenyl)-3-methyl-1,2-butanediamine]ruthenium(II) RuCl2[(R)-dm-segphos][(R)-daipen]
Dichloro{(R)-(+)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole}[(2R)-(-)-1,1-bis(4-methoxyphenyl)-3-methyl-1,2-butanediamine]ruthenium(II) RuCl2[(R)-dm-segphos][(R)-daipen] Basic information
- Product Name:
- Dichloro{(R)-(+)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole}[(2R)-(-)-1,1-bis(4-methoxyphenyl)-3-methyl-1,2-butanediamine]ruthenium(II) RuCl2[(R)-dm-segphos][(R)-daipen]
- Synonyms:
-
- Dichloro{(R)-(+)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole}[(2R)-(-)-1,1-bis(4-methoxyphenyl)-3-methyl-1,2-butanediamine]ruthenium(II) RuCl2[(R)-dm-segphos][(R)-daipen]
- RuCl2[(R)-DM-SEGPHOS ][(R)-DAIPEN]
- RUCL2[(R)-DM-SEGPHOS][(R)-DAIPEN]
- RuCl2[(R)-dm-segphos(regR)][(R)-daipen]
- Dichloro{(R)-(+)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole}[(2R)-(-)-1,1-bis(4-methoxyphenyl)-3-methyl-1,2-butanediamine]ruthenium(II) RuCl2[(R)-dm-segphos(R)][(R)-daipen]
- RuCl2[(R)-dm-segphos(regR)][(R)-daipen] RuCl2[(R)-dm-segphos][(R)-daipen]
- trans-RuCl2[(R)-dm-segphos][(R)-daipen]
- Dichloro{(R)-(+)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole}[(2R)-(-)-1,1-bis(4-methoxyphenyl)-3-methyl-1,2-butanediamine]ruthenium(II) RuCl2[(R)-dm-segphos][(R)-daipen
- CAS:
- 944450-43-5
- MF:
- C65H70Cl2N2O6P2Ru
- MW:
- 1209.184622
- Mol File:
- 944450-43-5.mol
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Dichloro{(R)-(+)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole}[(2R)-(-)-1,1-bis(4-methoxyphenyl)-3-methyl-1,2-butanediamine]ruthenium(II) RuCl2[(R)-dm-segphos][(R)-daipen] Chemical Properties
- storage temp.
- 2-8°C
- form
- Powder
- color
- yellow
- Sensitive
- air sensitive
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Dichloro{(R)-(+)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole}[(2R)-(-)-1,1-bis(4-methoxyphenyl)-3-methyl-1,2-butanediamine]ruthenium(II) RuCl2[(R)-dm-segphos][(R)-daipen] Usage And Synthesis
Reaction
- Biaryl bisphosphine ligand with narrow dihedral angle. The DM-SEGPHOS ligand, as the ruthenium complex, gives superior enantioselectivity and diastereoselectivity in the asymmetric hydrogenation of α-substituted-β-ketoesters.
- Ruthenium catalyzed enantioselective synthesis of β amino acids by hydrogenation.
- Ruthenium catalyzed asymmetric hydrogenation of 3-quinuclidinone.
Dichloro{(R)-(+)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole}[(2R)-(-)-1,1-bis(4-methoxyphenyl)-3-methyl-1,2-butanediamine]ruthenium(II) RuCl2[(R)-dm-segphos][(R)-daipen]Supplier
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Sigma-Aldrich
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Dichloro{(R)-(+)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole}[(2R)-(-)-1,1-bis(4-methoxyphenyl)-3-methyl-1,2-butanediamine]ruthenium(II) RuCl2[(R)-dm-segphos][(R)-daipen](944450-43-5)Related Product Information
- Carbonylhydrido(tetrahydroborato)[bis(2-diphenylphosphinoethyl) aMino]rutheniuM(II), Min.98% Ru-MACHO BH
- Dichloro{(S)-(-)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole} [(1S,2S)-(-)-1,2-diphenylethylenediamine]ruthenium(II) RuCl2[(S)-dm-segphos][(S,S)-dpen]
- Dichloro{(S)-(-)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole}[(2S)-(+)-1,1-bis(4-methoxyphenyl)-3-methyl-1,2-butanediamine]ruthenium(II)
- Dichloro{(R)-(+)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole}[(1R,2R)-(+)-1,2-diphenylethylenediamine]ruthenium(II) RuCl2[(R)-dm-segphos][(R,R)-dpen]