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1,4-Thioxane-1,1-dioxide

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1,4-Thioxane-1,1-dioxide Basic information

Product Name:
1,4-Thioxane-1,1-dioxide
Synonyms:
  • oxathiane4,4-dioxide
  • p-thioxanesulfone
  • thioxanesulfone
  • usafdo-38
  • 1,4-OXATHIANE 4,4-DIOXIDE
  • 1,4LAMBDA6-OXATHIANE-4,4-DIONE
  • 1,4-THIOXANE 1,1-DIOXIDE
  • 4,4-DIOXO-1,4-OXATHIANE
CAS:
107-61-9
MF:
C4H8O3S
MW:
136.17
EINECS:
203-507-7
Mol File:
107-61-9.mol
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1,4-Thioxane-1,1-dioxide Chemical Properties

Melting point:
131-133 °C
Boiling point:
220.45°C (rough estimate)
Density 
1.283 (estimate)
refractive index 
1.4640 (estimate)
storage temp. 
Inert atmosphere,Room Temperature
form 
solid
color 
White to Almost white
BRN 
110609
CAS DataBase Reference
107-61-9(CAS DataBase Reference)
EPA Substance Registry System
1,4-Oxathiane, 4,4-dioxide (107-61-9)
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Safety Information

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
24/25
RTECS 
RP4375000
TSCA 
Yes
HS Code 
2934999090
Toxicity
mouse,LD50,intraperitoneal,200mg/kg (200mg/kg),National Technical Information Service. Vol. AD277-689,

MSDS

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1,4-Thioxane-1,1-dioxide Usage And Synthesis

Description

1,4-Thioxane-1,1-dioxide is a heterocyclic compound with sulfur and oxygen.

Chemical Properties

White to Almost white powder to crystal

Definition

ChEBI: 1,4Lambda~6~-oxathiane-4,4-dione is an oxacycle and an organosulfur heterocyclic compound.

Hazard

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Synthesis

The synthesis of 1,4-Thioxane-1,1-dioxide is as follows:
From 208 grams1,4-thioxane with 300 ml of acetic acid and 400 ml mass concentration 30% hydrogen peroxide was stirred at room temperature 2 days. The solvent was evaporated to dryness and recrystallized from dichloromethane-cyclohexane1,4-thioxane-1,1-dioxane 204 g, melting point 76-78 °C, yield 70%.

storage

ventilated warehouse; keep away from sunshine; avoid fire; avoid moisture

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