Basic information Reaction Safety Supplier Related

(R)-(-)-1-[(R)-2-(2'-Diphenylphosphinophenyl)ferrocenyl]ethylbis(di-3,5-trifluoromethylphenyl)phosphine

Basic information Reaction Safety Supplier Related

(R)-(-)-1-[(R)-2-(2'-Diphenylphosphinophenyl)ferrocenyl]ethylbis(di-3,5-trifluoromethylphenyl)phosphine Basic information

Product Name:
(R)-(-)-1-[(R)-2-(2'-Diphenylphosphinophenyl)ferrocenyl]ethylbis(di-3,5-trifluoromethylphenyl)phosphine
Synonyms:
  • (R)-1-[(R)-1-[Bis[3,5- bis(trifluoromethyl)phenyl]phosp hino]ethyl]-2-[2- (diphenylphosphino)phenyl]ferro cene
  • (R)-(-)-1-[(R)-2-(2'-Diphenylphosphinophenyl)ferrocenyl]ethylbis(di-3,5-trifluoroMethylphenyl)phosphine
  • (R)-(-)-1-[(R)-2-(2'-Diphenylphosphinophenyl)ferrocenyl]ethylbis(di-3,5-trifluoromethylphenyl)phosphine, Walphos SL-W001-1
  • SL-W001-1
  • (R)-(-)-1-[(Rp)-2-(2'-Diphenylphosphinophenyl)ferrocenyl]ethylbis(di-3,5-trifluoromethylphenyl)phosphine
  • (R)-(-)-1-[(R)-2-(2''-Diphenylphosphinophenyl)ferrocenyl]ethylbis(di-3,5-trifluoromethylphenyl)phosphine
CAS:
565184-33-0
MF:
C46H26F12FeP2
MW:
924.49
Mol File:
565184-33-0.mol
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(R)-(-)-1-[(R)-2-(2'-Diphenylphosphinophenyl)ferrocenyl]ethylbis(di-3,5-trifluoromethylphenyl)phosphine Chemical Properties

Melting point:
81-87 °C
alpha 
-2° ±0.5° (c 0.5, CHCl3)
form 
Powder
color 
orange
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(R)-(-)-1-[(R)-2-(2'-Diphenylphosphinophenyl)ferrocenyl]ethylbis(di-3,5-trifluoromethylphenyl)phosphine Usage And Synthesis

Reaction

  1. Ligand for Rhodium-catalyzed enantioselective synthesis of spirocyclic benzopyranones by intermolecular[4+2]annulation
  2. Ligand for Copper-catalyzed enantioselective synthesis of α-heteroarylpyrrolidines by 1,3-cycloaddition of α-silylimines
  3. Ligand for Silver-catalyzed enantioselective propargylation reactions of N-sulfonylketimines
  4. Ligand for Rhodium-catalyzed enantioselective addition of arylboronic acids to cyclic ketimines

(R)-(-)-1-[(R)-2-(2'-Diphenylphosphinophenyl)ferrocenyl]ethylbis(di-3,5-trifluoromethylphenyl)phosphineSupplier

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