1,3,5,7-Tetramethyl-8-(2-di-o-tolylphosphinophenyl)-2,4,6-trioxa-8-phosphaadamantane PAd-DalPhos
1,3,5,7-Tetramethyl-8-(2-di-o-tolylphosphinophenyl)-2,4,6-trioxa-8-phosphaadamantane PAd-DalPhos Basic information
- Product Name:
- 1,3,5,7-Tetramethyl-8-(2-di-o-tolylphosphinophenyl)-2,4,6-trioxa-8-phosphaadamantane PAd-DalPhos
- Synonyms:
-
- 1,3,5,7-TETRAMETHYL-8-(2-DI-O-TOLYLPHOSPHINOPHENYL)-2,4,6-TRIOXA-8-PHOSPHAADAMANTANEPAD-DALPHOS
- 2,4,6-Trioxa-8-phosphatricyclo[3.3.1.13,7]decane, 8-[2-[bis(2-methylphenyl)phosphino]phenyl]-1,3,5,7-tetramethyl-
- CAS:
- 1902911-38-9
- MF:
- C30H34O3P2
- MW:
- 504.54
- Mol File:
- 1902911-38-9.mol
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1,3,5,7-Tetramethyl-8-(2-di-o-tolylphosphinophenyl)-2,4,6-trioxa-8-phosphaadamantane PAd-DalPhos Chemical Properties
- Boiling point:
- 576.1±50.0 °C(Predicted)
- form
- Powder
- color
- white
- Sensitive
- air sensitive, moisture sensitive
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1,3,5,7-Tetramethyl-8-(2-di-o-tolylphosphinophenyl)-2,4,6-trioxa-8-phosphaadamantane PAd-DalPhos Usage And Synthesis
Uses
PAd-DalPhos is a versatile air stable pre-catalyst for C(sp2)-N coupling. It catalyzes N-arylation of amides with (hetero)aryl (pseudo)halide. It can also be used in the synthesis of unsymmetrical 1,3-di(hetero)aryl-1H-indazoles from hydrazine, o-chloro (hetero)benzophenones and (hetero)aryl bromides.