(R)-(+)-2,2',6,6'-TETRAMETHOXY-4,4'-BIS(DIPHENYLPHOSPHINO)-3,3'-BIPYRIDINE Chemical Properties

Melting point:

261-265°C

Boiling point:

686.1±55.0 °C(Predicted)

storage temp. 

under inert gas (nitrogen or Argon) at 2-8°C

pka

-2.99±0.20(Predicted)

form 

Powder

color 

white to pale yellow

optical activity

[α]20/D -98°, c = 1 in chloroform

Safety Information

Hazard Codes 

Xi

Risk Statements 

36/37/38-37

Safety Statements 

26-36/37/39

WGK Germany 

3

MSDS

• Language:English Provider:ALFA

(R)-(+)-2,2',6,6'-TETRAMETHOXY-4,4'-BIS(DIPHENYLPHOSPHINO)-3,3'-BIPYRIDINE Usage And Synthesis

Reaction

New class of highly effective chiral dipyridylphosphine ligands used in the asymmetric hydrogenation of 2-arylacrylic acids, β-ketoesters, and aryl ketones.

Chemical Properties

White solid

Uses

(S)-P-Phos can be used as a ligand:

• In the asymmetic hydrogenation reactions.
• For the preparation of chiral ketone functionalized polymers by copolymerization reaction.
• To synthesize chiral alkynes by asymmetric hydroalkynylation of nonpolar alkenes or norbornadienes using iridium catalyst.
• In the selective allylic alkylation of indoles using palladium catalyst.

(R)-(+)-2,2',6,6'-TETRAMETHOXY-4,4'-BIS(DIPHENYLPHOSPHINO)-3,3'-BIPYRIDINE(362524-23-0)Related Product Information

• (R)-(+)-2,2',6,6'-TETRAMETHOXY-4,4'-BIS(DIPHENYLPHOSPHINO)-3,3'-BIPYRIDINE
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