(11S,12S)-9,10-DIHYDRO-9,10-ETHANOANTHRACENE-11,12-DIAMINE Chemical Properties

Melting point:

158 °C

Boiling point:

396.7±42.0 °C(Predicted)

Density 

1.195±0.06 g/cm3(Predicted)

refractive index 

20 ° (C=1, MeOH)

storage temp. 

under inert gas (nitrogen or Argon) at 2–8 °C

form 

powder to crystal

pka

9.38±0.40(Predicted)

color 

White to Orange to Green

optical activity

Consistent with structure

BRN 

8693351

InChI

1S/C16H16N2/c17-15-13-9-5-1-2-6-10(9)14(16(15)18)12-8-4-3-7-11(12)13/h1-8,13-16H,17-18H2/t13-,14+,15-,16-/m1/s1

InChIKey

NWDYSRZJOLDMRE-QKPAOTATSA-N

SMILES

N[C@H]1[C@H](N)[C@H]2c3ccccc3[C@@H]1c4ccccc24

Safety Information

Hazard Codes 

Xi

Risk Statements 

36/37/38

Safety Statements 

26

WGK Germany 

3

HS Code 

2921.51.5000

Storage Class

13 - Non Combustible Solids

(11S,12S)-9,10-DIHYDRO-9,10-ETHANOANTHRACENE-11,12-DIAMINE Usage And Synthesis

Uses

(11S,12S)-9,10-Dihydro-9,10-ethanoanthracene-11,12-diamine is a chiral diamine, which can be used as a reactant:

• To synthesize pyridine based C₂-symmetrical chiral organocatalysts via palladium catalyzed coupling reaction with 2-bromo-4-(alkylamino)pyridine.
• To prepare porous organic imine cages by cycloimination reaction with triformylbenzene.
• To synthesize Ga/Yb-Schiff base complex, which is utilized as a catalyst for the asymmetric synthesis of 5-amino-2-(hydroxyalkyl)oxazoles by enantioselective α-addition of α-isocyano amides to aldehydes.

(11S,12S)-9,10-DIHYDRO-9,10-ETHANOANTHRACENE-11,12-DIAMINE(138517-66-5)Related Product Information

• N-BENZYLQUINIDINIUM CHLORIDE
• (11R,12R)-9,10-DIHYDRO-9,10-ETHANOANTHRACENE-11,12-DIAMINE
• (11S,12S)-9,10-DIHYDRO-9,10-ETHANOANTHRACENE-11,12-DIAMINE
• AURORA KA-7175