(11S,12S)-9,10-DIHYDRO-9,10-ETHANOANTHRACENE-11,12-DIAMINE
(11S,12S)-9,10-DIHYDRO-9,10-ETHANOANTHRACENE-11,12-DIAMINE Basic information
- Product Name:
- (11S,12S)-9,10-DIHYDRO-9,10-ETHANOANTHRACENE-11,12-DIAMINE
- Synonyms:
-
- (11S,12S)-11,12-diamino-9,10-dihydro-9,10-ethanoanthracene (R)-mandelate monoammonium salt
- (11S,12S)-9,10-DIHYDRO-9,10-ETHANOANTHRACENE-11,12-DIAMINE
- (S,S)-11,12-Diamino-9,10-dihydro-9,10-ethanoanthracene
- (11S,12S)-9,10-Dihydro-9,10-ethanoanthracene-11,12-diamine >=95.0% (HPLC)
- (11S,12S)-9,10-Dihydro-9,10-ethanoanthracene-11,12-diamine>
- 9,10-Ethanoanthracene-11,12-diamine, 9,10-dihydro-, (11S,12S)-
- CAS:
- 138517-66-5
- MF:
- C16H16N2
- MW:
- 236.31
- Product Categories:
-
- Asymmetric Synthesis
- Synthetic Organic Chemistry
- Mol File:
- 138517-66-5.mol
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(11S,12S)-9,10-DIHYDRO-9,10-ETHANOANTHRACENE-11,12-DIAMINE Chemical Properties
- Melting point:
- 158 °C
- Boiling point:
- 396.7±42.0 °C(Predicted)
- Density
- 1.195±0.06 g/cm3(Predicted)
- refractive index
- 20 ° (C=1, MeOH)
- storage temp.
- under inert gas (nitrogen or Argon) at 2–8 °C
- form
- powder to crystal
- pka
- 9.38±0.40(Predicted)
- color
- White to Orange to Green
- BRN
- 8693351
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(11S,12S)-9,10-DIHYDRO-9,10-ETHANOANTHRACENE-11,12-DIAMINE Usage And Synthesis
Uses
(11S,12S)-9,10-Dihydro-9,10-ethanoanthracene-11,12-diamine is a chiral diamine, which can be used as a reactant:
- To synthesize pyridine based C2-symmetrical chiral organocatalysts via palladium catalyzed coupling reaction with 2-bromo-4-(alkylamino)pyridine.
- To prepare porous organic imine cages by cycloimination reaction with triformylbenzene.
- To synthesize Ga/Yb-Schiff base complex, which is utilized as a catalyst for the asymmetric synthesis of 5-amino-2-(hydroxyalkyl)oxazoles by enantioselective α-addition of α-isocyano amides to aldehydes.
(11S,12S)-9,10-DIHYDRO-9,10-ETHANOANTHRACENE-11,12-DIAMINESupplier
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