Methoxytriethyleneoxypropyltrimethoxysilane Chemical Properties

Boiling point:

140°C/0.2mmHg

Density 

1.163

refractive index 

1.4321

Specific Gravity

1.163

Hydrolytic Sensitivity

7: reacts slowly with moisture/water

InChI

InChI=1S/C13H30O7Si/c1-14-7-8-19-11-12-20-10-9-18-6-5-13-21(15-2,16-3)17-4/h5-13H2,1-4H3

InChIKey

KRIUTXYABPSKPN-UHFFFAOYSA-N

SMILES

CO[Si](OC)(OC)CCCOCCOCCOCCOC

Safety Information

TSCA 

No

Methoxytriethyleneoxypropyltrimethoxysilane Usage And Synthesis

Uses

Methoxytriethyleneoxypropyltrimethoxysilane (MTE-TMS), a novel multifunctional additive possessing a unique functionality to simultaneously protect both Ni-rich NCM and graphite electrode surfaces. MTE-TMS improves the long-term cycling stability not only of individual half-cells of graphite and Ni-rich NCM but also of the full graphite‖Ni-rich NCM cell.

Properties and Applications

Ex-situ analysis showed that Methoxytriethyleneoxypropyltrimethoxysilane (MTE-TMS) forms a stable and thin surface protective film on the NCM851005, containing Si species, which effectively reduced crack formation, metal dissolution, and structural degradation of the cathode. MTE-TMS also forms a stable SEI layer on the graphite anode, stabilizing the graphite structure and preventing the thickening of the SEI. MTE-TMS’ effectivity, on both anode and cathode, results in superior cycling performance of the full-cells, with 1 wt% MTE-TMS in the electrolyte, delivering a high capacity of 198 mAh g^?1, along with an excellent capacity retention of 84% after 100 cycles at C/5, while cycled to upper cut-off voltage of 4.25 V (4.3 vs Li⁺/Li). MTE-TMS has the potential to help the realization of high energy density Li-ion batteries by enabling a wider working voltage range for Ni-rich oxide cathodes[1].

References

[1] Hieu Quang Pham . “Multifunctional electrolyte additive for improved interfacial stability in Ni-rich layered oxide full-cells.” Energy Storage Materials 33 (2020): Pages 216-229.

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