Bis[di-(tert-butyl)(4-trifluoromethylphenyl)phosphine]palladium(II) chloride Chemical Properties

Melting point:

230 °C (D)

storage temp. 

under inert gas (nitrogen or Argon) at 2-8°C

form 

powder

InChI

1S/2C15H22F3P.2ClH.Pd/c2*1-13(2,3)19(14(4,5)6)12-9-7-11(8-10-12)15(16,17)18;;;/h2*7-10H,1-6H3;2*1H;/q;;;;+2/p-2

InChIKey

ATVRGWRBZLLSJD-UHFFFAOYSA-L

SMILES

Cl[Pd]Cl.CC(C)(C)P(c1ccc(cc1)C(F)(F)F)C(C)(C)C.CC(C)(C)P(c2ccc(cc2)C(F)(F)F)C(C)(C)C

Safety Information

Hazard Codes 

Xi

Risk Statements 

36/37/38

Safety Statements 

26

WGK Germany 

3

Storage Class

11 - Combustible Solids

Hazard Classifications

Eye Irrit. 2
Skin Irrit. 2
STOT SE 3

Bis[di-(tert-butyl)(4-trifluoromethylphenyl)phosphine]palladium(II) chloride Usage And Synthesis

Uses

Catalyst for Suzuki Coupling reaction of heteroaryl chlorides

reaction suitability

core: palladium
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst
reaction type: Cross Couplings

Bis[di-(tert-butyl)(4-trifluoromethylphenyl)phosphine]palladium(II) chloride(887919-36-0)Related Product Information

• Bis[Tris(2-methylphenyl)phosphine]palladium
• Di-Mu-chlorobis(2'-aMino-1,1'-biphenyl-2-yl-C,N)dipalladiuM(II)
• (4-TRIFLUOROMETHYLPHENYL)PHOSPHINE