DIMETHYL 2,6-DIBROMOHEPTANEDIOATE
DIMETHYL 2,6-DIBROMOHEPTANEDIOATE Basic information
- Product Name:
- DIMETHYL 2,6-DIBROMOHEPTANEDIOATE
- Synonyms:
-
- DIMETHYL 2,6-DIBROMOHEPTANEDIOATE
- dimethyl 2,6-dibromoheptanedionate
- 2,6-dibromoheptanedioic acid dimethyl ester
- 2,6-Dibromoheptadioic acid dimethyl ester
- 2,6-Dibromopimelic acid dimethyl ester
- DiMethyl 2,6-dibroMoheptanedioate 97%
- Heptanedioic acid,2,6-dibromo-, 1,7-dimethyl ester
- CAS:
- 868-73-5
- MF:
- C9H14Br2O4
- MW:
- 346.01
- Mol File:
- 868-73-5.mol
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DIMETHYL 2,6-DIBROMOHEPTANEDIOATE Chemical Properties
- Boiling point:
- 130-140 °C0.01 mm Hg(lit.)
- Density
- 1.59 g/mL at 25 °C(lit.)
- refractive index
- n20/D 1.501(lit.)
- Flash point:
- >230 °F
- storage temp.
- Inert atmosphere,Room Temperature
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Safety Information
- Hazard Codes
- Xn
- Risk Statements
- 22-36/37/38
- Safety Statements
- 26
- RIDADR
- UN 3334
- WGK Germany
- 3
MSDS
- Language:English Provider:SigmaAldrich
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DIMETHYL 2,6-DIBROMOHEPTANEDIOATE Usage And Synthesis
Uses
Dimethyl 2,6-dibromoheptanedioate may be used in the following studies:
- Preparation of difunctional poly(n-butyl acrylate) (pBA) macroinitiator.
- As initiator for the synthesis of dibromo-terminated polystyrene, via atom transfer radical polymerization (ATRP).
- Preparation of polytrithiocarbonate, which serves as Reversible Addition-Fragmentation chain Transfer (RAFT) agent for radical polymerization reactions.
General Description
Dimethyl 2,6-dibromoheptanedioate acts as a bifunctional initiator in various polymerization reactions. Its electrochemical cyclization affords high yields of three- to six-membered dimethyl 1,2-cycloalkanedicarboxylates.
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