Basic information Safety Supplier Related

(1S,2S)-(+)-2-AMINO-1-[4-(METHYLTHIO)PHENYL]-1,3-PROPANEDIOL

Basic information Safety Supplier Related

(1S,2S)-(+)-2-AMINO-1-[4-(METHYLTHIO)PHENYL]-1,3-PROPANEDIOL Basic information

Product Name:
(1S,2S)-(+)-2-AMINO-1-[4-(METHYLTHIO)PHENYL]-1,3-PROPANEDIOL
Synonyms:
  • 2-Amino-1-[4-(methylthio)phenyl]-1,3-propanediol
  • [S(R*,R*)]-2-amino-1-[p-(methylthio)phenyl]propane-1,3-diol
  • L-THIOMICAMINE
  • (1S,2S)-(+)-THIOMICAMINE
  • (1S,2S)-(+)-2-AMINO-1-[4-(METHYLTHIO)PHENYL]-1,3-PROPANEDIOL
  • thiomicamine
  • (1S,2S)-1-[4-(Methylthio)phenyl]-2-amino-1,3-propanediol
  • (1S,2S)-1-[4-(Methylthio)phenyl]-2-aminopropane-1,3-diol
CAS:
16854-32-3
MF:
C10H15NO2S
MW:
213.3
EINECS:
240-878-4
Mol File:
16854-32-3.mol
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(1S,2S)-(+)-2-AMINO-1-[4-(METHYLTHIO)PHENYL]-1,3-PROPANEDIOL Chemical Properties

Melting point:
151-154 °C(lit.)
Boiling point:
428.2±45.0 °C(Predicted)
Density 
1.25±0.1 g/cm3(Predicted)
pka
11.75±0.45(Predicted)
optical activity
[α]25/D +25°, c = 1 in ethanol
CAS DataBase Reference
16854-32-3(CAS DataBase Reference)
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Safety Information

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-37/39
WGK Germany 
3
HS Code 
2930909899

MSDS

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(1S,2S)-(+)-2-AMINO-1-[4-(METHYLTHIO)PHENYL]-1,3-PROPANEDIOL Usage And Synthesis

Uses

(1S,2S)-(+)-Thiomicamine can be used:

  • As a starting material in the synthesis of 3,4-dihydroisoquinolinium salts, which are employed as promoters in asymmetric epoxidation and oxidation?reactions.
  • As a starting material in the synthesis of an α-amino acid named (3R,4R)-4-phenyl-1,2,3,4-tetrahydroisoquinoline-3-carboxylic acid, which is used to prepare modified peptides of biological importance.
  • As a chiral base in the resolution of an angiotensin II type 2 receptor [AT2R] antagonist named EMA401.

(1S,2S)-(+)-2-AMINO-1-[4-(METHYLTHIO)PHENYL]-1,3-PROPANEDIOLSupplier

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