Basic information Safety Supplier Related

TETRATHIAFULVALENE

Basic information Safety Supplier Related

TETRATHIAFULVALENE Basic information

Product Name:
TETRATHIAFULVALENE
Synonyms:
  • 1,3-Dithiole, 2-(1,3-dithiol-2-ylidene)-
  • 1,4,5,8-Tetrathiafulvalen
  • 1,4,5,8-Tetrathiafulvalene
  • 2-(1,3-dithiol-2-ylidene)-1,3-dithiol
  • Δ2,2μ-Bi-1,3-dithiole, TTF
  • Delta2,2'-bi-1,3-dithiol
  • [2,2']-Bi[1,3]-dithioylidene
  • Tetrathiafulvalene, 99+% 1GR
CAS:
31366-25-3
MF:
C6H4S4
MW:
204.34
EINECS:
250-593-7
Product Categories:
  • Functional Materials
  • TTF Derivatives
  • Building Blocks
  • Chemical Synthesis
  • Heterocyclic Building Blocks
  • Materials Science
  • Charge Transfer Complexes for Organic Metals
  • Donors (Charge Transfer Complexes)
  • Organic and Printed Electronics
  • Organic Field Effect Transistor (OFET) Materials
  • Others
  • p-Type Organic Semiconductors
  • p-Type Small Molecules
  • S-Containing
Mol File:
31366-25-3.mol
More
Less

TETRATHIAFULVALENE Chemical Properties

Melting point:
116-119 °C (lit.)
Boiling point:
90℃ (1 Torr)
Density 
1.448 (estimate)
refractive index 
1.6000 (estimate)
storage temp. 
2-8°C
form 
Crystals or Crystalline Powder
color 
Orange to brownish
Water Solubility 
It is insoluble in water. Soluble in organic solvents.
Sensitive 
Air & Light Sensitive
λmax
369nm(CHCl3)(lit.)
Merck 
14,9242
BRN 
1617956
InChIKey
FHCPAXDKURNIOZ-UHFFFAOYSA-N
CAS DataBase Reference
31366-25-3(CAS DataBase Reference)
EPA Substance Registry System
1,3-Dithiole, 2-(1,3-dithiol-2-ylidene)- (31366-25-3)
More
Less

Safety Information

Hazard Codes 
Xi
Risk Statements 
43-52/53
Safety Statements 
36/37-61-24/25
RIDADR 
3335
WGK Germany 
3
10-23
TSCA 
Yes
HS Code 
29309090

MSDS

More
Less

TETRATHIAFULVALENE Usage And Synthesis

Chemical Properties

ORANGE TO BROWNISH CRYSTALS OR CRYSTALLINE POWDER

Uses

Electron donor for supramolecular synthesis,1 charge-transfer complex synthesis2 with 7,7,8,8-tetracyanoquinodimethane (cat. no. 157635), and for electron transfer to diazonium salts.3

Uses

Tetrathiafulvalene, holds wide application in HPLC, NMR. This heterocyclic compound contributed to the development of molecular electronics. They are used as a organic super conductors.

Uses

Molecular sensors; radical catalyst.

Definition

ChEBI: Tetrathiafulvalene is a member of the class of fulvalenes that is ethene substituted by 1,3-dithiol-2-ylidene groups at positions 1 and 2. It is an organosulfur heterocyclic compound and a member of fulvalenes.

General Description

Tetrathiafulvalene (TTF) is an electron-donor which consists of oligomers, dendrimers and polymers which can be used in the formation of redox macromolecules.

Purification Methods

Recrystallise it from cyclohexane/hexane under an argon atmosphere [Kauzlarich et al. J Am Chem Soc 109 4561 1987]. [Beilstein 19/11 V 380.]

TETRATHIAFULVALENESupplier

Mianyang Vandino Pharmaceutical Technology Co., Ltd. Gold
Tel
18990175493 17883072998
Email
1755695756@qq.com
Energy Chemical Gold
Tel
021-58432009 400-005-6266
Email
marketing1@energy-chemical.com
Jilin Chinese Academy of Sciences - Yanshen Technology Co., Ltd Gold
Tel
0431-80514535 19917294565
Email
et@chemextension.com
Suzhou origin Specialty Chemicals Co., Ltd Gold
Tel
17701559125
Email
jiaoshangjun@origsc.com
J & K SCIENTIFIC LTD.
Tel
010-82848833 400-666-7788
Email
jkinfo@jkchemical.com