CIS-DICHLOROBIS(TRIPHENYLPHOSPHINE)PLATINUM(II) Chemical Properties

Melting point:

≥300 °C(lit.)

storage temp. 

under inert gas (nitrogen or Argon) at 2–8 °C

InChI

1S/2C18H15P.2ClH.Pt/c2*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;;;/h2*1-15H;2*1H;/q;;;;+2/p-2

InChIKey

XAFJSPPHVXDRIE-UHFFFAOYSA-L

SMILES

Cl[Pt]Cl.c1ccc(cc1)P(c2ccccc2)c3ccccc3.c4ccc(cc4)P(c5ccccc5)c6ccccc6

Safety Information

Hazard Codes 

Xi

Risk Statements 

36/37/38

Safety Statements 

26-37/39

WGK Germany 

3

Storage Class

11 - Combustible Solids

Hazard Classifications

Acute Tox. 4 Oral
Eye Irrit. 2
Resp. Sens. 1
Skin Irrit. 2
Skin Sens. 1
STOT RE 2
STOT SE 3

MSDS

• Language:English Provider:SigmaAldrich
• Language:English Provider:ALFA

CIS-DICHLOROBIS(TRIPHENYLPHOSPHINE)PLATINUM(II) Usage And Synthesis

Uses

Catalyst for:

• Preparation of soluble polymers of monosubstituted acetylenes with quaternary ammonium pendant groups
• Alkynylation and hydrogenation reactions
• Hetero-Diels-Alder/ring-opening reactions
• Insertion of carbenes into O-H bonds of alcohols
• Cyclopropanation of olefins
• Hydroformylation reactions

reaction suitability

core: platinum
reagent type: catalyst

CIS-DICHLOROBIS(TRIPHENYLPHOSPHINE)PLATINUM(II)(14056-88-3)Related Product Information

• Platinum dichloride
• (FORMYLMETHYLENE)TRIPHENYLPHOSPHORANE
• Platinum
• TRIPHENYLPHOSPHINE HYDROCHLORIDE
• CIS-DICHLOROBIS(TRIPHENYLPHOSPHINE)PLATINUM(II)