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DIETHYLALUMINUM ETHOXIDE

Basic information Safety Supplier Related

DIETHYLALUMINUM ETHOXIDE Basic information

Product Name:
DIETHYLALUMINUM ETHOXIDE
Synonyms:
  • uminum ethoxide
  • 25%w/winhexane
  • Diethylaluminium ethoxide, 1.3M solution in hexane
  • Diethylaluminium ethoxide1.3M solution in hexaneAcroSeal§3
  • Diethylethoxyaluminum
  • Diethylaluminium ethoxide, 25 wt% solution in toluene
  • diethylaluminum ethoxide solution
  • Diethylaluminiumethoxid
CAS:
1586-92-1
MF:
C6H15AlO
MW:
130.16
EINECS:
216-447-1
Product Categories:
  • Chemical Synthesis
  • AluminumChemical Synthesis
  • Micro/Nanoelectronics
  • Organoaluminum
  • Organometallic Reagents
  • Solution Deposition Precursors
  • Organometallics
  • Aluminum
  • Chemical Synthesis
  • Materials Science
  • Organometallic Reagents
  • Solution Deposition Precursors
Mol File:
1586-92-1.mol
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DIETHYLALUMINUM ETHOXIDE Chemical Properties

Melting point:
2.5-4.5 °C(lit.)
Boiling point:
108-109 °C/10 mmHg(lit.)
Density 
0.862 g/mL at 25 °C
vapor pressure 
5 mm Hg ( 94 °C)
Flash point:
−1 °F
storage temp. 
0-6°C
solubility 
Soluble in hydrocarbons and ether.
form 
Liquid
color 
Colorless
Sensitive 
Air & Moisture Sensitive
Exposure limits
ACGIH: TWA 50 ppm (Skin)
OSHA: TWA 500 ppm(1800 mg/m3)
NIOSH: IDLH 1100 ppm; TWA 50 ppm(180 mg/m3)
EPA Substance Registry System
Aluminum, ethoxydiethyl- (1586-92-1)
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Safety Information

Hazard Codes 
F,T,C
Risk Statements 
11-14-17-23/24/25-34-14/15-67-65-48/20-63
Safety Statements 
16-26-36/37/39-45-43-27-62
RIDADR 
UN 3394 4.2/PG 1
WGK Germany 
nwg
TSCA 
Yes
HazardClass 
4.3
PackingGroup 
I
HS Code 
29319090

MSDS

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DIETHYLALUMINUM ETHOXIDE Usage And Synthesis

Chemical Properties

colorless liquid

Uses

Diethylaluminum ethoxide is a base in aldol condensation reactions; it can be used as a reducing agent in the preparation of Ni catalysts.

Flammability and Explosibility

Spontaneously flammable in air (pyrophoric)

storage

The reagent itself is pyrophoric and its solutions are highly flammable  and air and moisture sensitive and should be handled under an inert atmosphere. Use in a fume hood.

DIETHYLALUMINUM ETHOXIDESupplier

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