Basic information Safety Supplier Related

(S)-N,N-DIMETHYL-1-[(R)-1',2-BIS(DIPHENYLPHOSPHINO)FERROCENYL]ETHYLAMINE

Basic information Safety Supplier Related

(S)-N,N-DIMETHYL-1-[(R)-1',2-BIS(DIPHENYLPHOSPHINO)FERROCENYL]ETHYLAMINE Basic information

Product Name:
(S)-N,N-DIMETHYL-1-[(R)-1',2-BIS(DIPHENYLPHOSPHINO)FERROCENYL]ETHYLAMINE
Synonyms:
  • (2S)-1-[(1S)-1-(Dimethylamino)ethyl]-1',2-bis(diphenylphosphino)ferrocene
  • (S)-N,N-Dimethyl-1-[(R)-1',2-bis(diphenylphosphino)ferrocenyl]ethylamine,95%
  • (+)-(S)-N,N-Dimethyl-1-[(R)-1
  • (+)-(S)-N,N-Dimethyl-1-[(R)-1',2-bis(diphenylphosphino)ferrocenyl]ethylamine 95%
  • (+)-(S)-N,N-DIMETHYL-1-[(R)-1',2-BIS(DIPHENYLPHOSPHINO)FERROCENYL]ETHYLAMINE
  • (S)-(R)-BPPFA
  • (+)-(S)-N,N-dimethyl-1-((R)-1',2-bis(di-phenylpho
  • (S,R)-1-(1-dimethylaminoethyl)-1,2-*bis(diphenyl
CAS:
55650-59-4
MF:
C38H37FeNP210*
MW:
625.5
Product Categories:
  • Chiral Phosphine
  • Asymmetric Synthesis
  • Classes of Metal Compounds
  • Fe (Iron) Compounds
  • Ferrocenes
  • Metallocenes
  • Phosphine Ligands
  • Synthetic Organic Chemistry
  • Transition Metal Compounds
  • Asymmetric Synthesis
  • Chiral Catalysts, Ligands, and Reagents
  • Other Chiral Ligands
Mol File:
55650-59-4.mol
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(S)-N,N-DIMETHYL-1-[(R)-1',2-BIS(DIPHENYLPHOSPHINO)FERROCENYL]ETHYLAMINE Chemical Properties

Melting point:
138-142 °C(lit.)
storage temp. 
under inert gas (nitrogen or Argon) at 2–8 °C
form 
solid
color 
Light yellow to Brown
optical activity
[α]20/D +350°, c = 0.5 in chloroform
InChIKey
VUJPTJYMSBMZOZ-RMRYJAPISA-N
SMILES
[Fe].[CH]1[CH][CH][C]([CH]1)P(c2ccccc2)c3ccccc3.C[C@@H]([C]4[CH][CH][CH][C]4P(c5ccccc5)c6ccccc6)N(C)C
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Safety Information

Hazard Codes 
Xn
Risk Statements 
20/21/22-36/37/38
Safety Statements 
26-36
WGK Germany 
3
HS Code 
29319090
Storage Class
11 - Combustible Solids
Hazard Classifications
Acute Tox. 4 Dermal
Acute Tox. 4 Inhalation
Acute Tox. 4 Oral
Eye Irrit. 2
Skin Irrit. 2
STOT SE 3

MSDS

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(S)-N,N-DIMETHYL-1-[(R)-1',2-BIS(DIPHENYLPHOSPHINO)FERROCENYL]ETHYLAMINE Usage And Synthesis

Uses

Ligand used in the asymmetric hydrogenation of (Z)-α-amido-cinnamic acids

(S)-N,N-DIMETHYL-1-[(R)-1',2-BIS(DIPHENYLPHOSPHINO)FERROCENYL]ETHYLAMINESupplier

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