TRIPHENYLARSINE
TRIPHENYLARSINE Basic information
- Product Name:
- TRIPHENYLARSINE
- Synonyms:
-
- TRIPHENYLARSINE FOR SYNTHESIS
- NSC 478
- Triphenylarsane
- Triphenyl-arsane
- Triphenylarsenic
- triphenyl-arsin
- ARSINETRIPHENYL
- ARSENIC TRIPHENYL
- CAS:
- 603-32-7
- MF:
- C18H15As
- MW:
- 306.23
- EINECS:
- 210-032-9
- Product Categories:
-
- As (Arsenic) Compounds
- Classes of Metal Compounds
- Semimetal Compounds
- organoarsenic compound
- Mol File:
- 603-32-7.mol
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TRIPHENYLARSINE Chemical Properties
- Melting point:
- 58-61 °C (lit.)
- Boiling point:
- 360 °C
- Density
- 1,225 g/cm3
- refractive index
- 1.6888
- Flash point:
- 265 °C
- storage temp.
- Store below +30°C.
- form
- Powder
- Specific Gravity
- 1.2225
- color
- white
- Water Solubility
- Soluble in methanol. Insoluble in water.
- Hydrolytic Sensitivity
- 4: no reaction with water under neutral conditions
- BRN
- 1842037
- CAS DataBase Reference
- 603-32-7(CAS DataBase Reference)
- EPA Substance Registry System
- Arsine, triphenyl- (603-32-7)
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Safety Information
- Hazard Codes
- T,N
- Risk Statements
- 23/25-50/53
- Safety Statements
- 20/21-28-45-60-61
- RIDADR
- UN 3465 6.1/PG 2
- WGK Germany
- 3
- RTECS
- CH8942500
- TSCA
- Yes
- HS Code
- 2931 90 00
- HazardClass
- 6.1
- PackingGroup
- II
MSDS
- Language:English Provider:SigmaAldrich
- Language:English Provider:ACROS
- Language:English Provider:ALFA
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TRIPHENYLARSINE Usage And Synthesis
Reaction
- Useful as a ligand in Stille coupling reactions.
- Synthesis of functionalized cyclopropanes from the reaction between acetylenic esters and C-H acids.
- Rh-complex catalyzed addition reactions of chloroacetyl chlorides to alkynes.
Chemical Properties
COLOURLESS TO SLIGHTLY YELLOW CRYSTALLINE SOLID
Uses
Triphenylarsine is used in certain metal-catalyzed coupling reactions. It is a precursor to tetraphenylarsonium chloride a popular precipitating agent.
Purification Methods
Recrystallise Ph3As from EtOH or aqueous EtOH [Dahlinger et al. J Chem Soc, Dalton Trans 2145 1986, Boert et al. J Am Chem Soc 109 7781 1987]. [Beilstein 16 H 829, 16 I 431, 16 II 407, 16 III 921, 16 IV 1139.] HIGHLY TOXIC.
TRIPHENYLARSINESupplier
J & K SCIENTIFIC LTD.
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- 010-82848833 400-666-7788
- jkinfo@jkchemical.com
Meryer (Shanghai) Chemical Technology Co., Ltd.
- Tel
- 4006608290; 18621169109
- market03@meryer.com
Alfa Aesar
- Tel
- 400-6106006
- saleschina@alfa-asia.com
TCI (Shanghai) Development Co., Ltd.
- Tel
- 021-67121386
- Sales-CN@TCIchemicals.com
Energy Chemical
- Tel
- 021-021-58432009 400-005-6266
- sales8178@energy-chemical.com
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TRIPHENYLARSINE(603-32-7)Related Product Information
- ARSENIC (III) SELENIDE
- CACODYLIC ACID
- TRIMETHYLARSINE
- ARSINE
- TETRAPHENYLARSONIUM CHLORIDE HYDROCHLORIDE
- TETRAPHENYLARSONIUM CHLORIDE MONOHYDRATE
- TETRAPHENYLARSONIUM CHLORIDE
- METHYLTRIPHENYLARSONIUM IODIDE
- TRIPHENYLARSINE OXIDE
- TRIPHENYLARSINE
- TETRAPHENYLARSONIUM BROMIDE
- TRI-(4-METHYLPHENYL)ARSINE
- chlorotris(triphenylarsine)rhodium
- Tungsten,pentacarbonyl(triphenylarsine)-(OC-6-22)-
- Phenylarsine
- TETRAPHENYLARSONIUM CHLORIDE HYDROCHLORIDE DIHYDRATE
- METHYL TRIPHENYLARSONIUM CHLORIDE
- TRI(3-METHYLPHENYL)ARSINE