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3-(BroMoMethyl)-5-Methylpyridine hydrobroMide

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3-(BroMoMethyl)-5-Methylpyridine hydrobroMide Basic information

Product Name:
3-(BroMoMethyl)-5-Methylpyridine hydrobroMide
Synonyms:
  • 3-(BroMoMethyl)-5-Methylpyridine hydrobroMide
  • 3-(broMoMethyl)-5-Methylpyridine HBr
  • 3-(Bromomethyl)-5-methylpyridine hydrobromide (1:1)
  • Fumarate R Impurity 2
  • Rupatadine impurity 4
  • Fumarate Impurity 2
  • -5-methylpyridine hydrobromide
  • Rupatadine Impurity 6 HBr
CAS:
1235342-53-6
MF:
C7H9Br2N
MW:
266.96
Product Categories:
  • DCP
Mol File:
1235342-53-6.mol
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3-(BroMoMethyl)-5-Methylpyridine hydrobroMide Chemical Properties

storage temp. 
under inert gas (nitrogen or Argon) at 2-8°C
InChI
InChI=1S/C7H8BrN.BrH/c1-6-2-7(3-8)5-9-4-6;/h2,4-5H,3H2,1H3;1H
InChIKey
CKEAZZPEMCPDPI-UHFFFAOYSA-N
SMILES
C(C1=CN=CC(C)=C1)Br.Br
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3-(BroMoMethyl)-5-Methylpyridine hydrobroMide Usage And Synthesis

Synthesis

102074-19-1

1235342-53-6

Step 2: Dissolve 5-methyl-3-pyridine methanol (10 mmol) in 10 mL of 40% aqueous hydrobromic acid and react at reflux for 5 h. The reaction was monitored by TLC or LC-MS. Upon completion of the reaction, the mixture was heated to remove the solvent (water and excess hydrobromic acid) by evaporation until the mixture became viscous. After cooling, acetone was added to the mixture to precipitate the product, the solid was collected by filtration and dried to give 3-(bromomethyl)-5-methylpyridine hydrobromide in up to 80% yield.

References

[1] Patent: WO2012/97196, 2012, A1. Location in patent: Page/Page column 34

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