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COBALT(II) FLUORIDE TETRAHYDRATE

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COBALT(II) FLUORIDE TETRAHYDRATE Basic information

Product Name:
COBALT(II) FLUORIDE TETRAHYDRATE
Synonyms:
  • Cobalt(II) fluoride tetrahydrate 99.99% trace metals basis
  • COBALTOUS FLUORIDE 4H2O
  • COBALT(II) FLUORIDE TETRAHYDRATE
  • Cobalt difluoride hydrate
  • Cobaltous fluoride tetrahydrate
  • Cobaltfluoridetetrahydrate
  • cobalt(ii) fluoride tetrahydrate, puratronic
  • Cobalt(II) fluoride tetrahydrate, Puratronic(R), 99.99% (metals basis)
CAS:
13817-37-3
MF:
CoF2H8O4
MW:
168.99
EINECS:
626-075-5
Product Categories:
  • Cobalt Salts
  • Metal and Ceramic Science
  • Salts
Mol File:
13817-37-3.mol
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COBALT(II) FLUORIDE TETRAHYDRATE Chemical Properties

Melting point:
200°C
Boiling point:
decomposes [MER06]
Density 
2.19 g/mL at 25 °C(lit.)
form 
Powder
color 
Pink
Specific Gravity
2.19
Water Solubility 
soluble H2O [MER06]
Sensitive 
Moisture Sensitive
Merck 
14,2440
Exposure limits
ACGIH: TWA 0.02 mg/m3
CAS DataBase Reference
13817-37-3(CAS DataBase Reference)
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Safety Information

Hazard Codes 
T
Risk Statements 
23/24/25-32-34
Safety Statements 
26-27-28-36/37/39-45
RIDADR 
UN 2923 8/PG 3
WGK Germany 
3
TSCA 
Yes
HazardClass 
6.1
PackingGroup 
III

MSDS

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COBALT(II) FLUORIDE TETRAHYDRATE Usage And Synthesis

Chemical Properties

Rose red crystal

Uses

Cobalt(II) fluoride tetrahydrate is used as a starting material to synthesize 2-dimensional cobalt-fluoride-oxide as an oxygen evolution electrocatalysts using a rapid thermal annealing (RTA) method. In this process, the cobalt(II) fluoride tetrahydrate is placed in an alumina furnace at 400°C. After annealing for 20 minutes in air, the alumina crucible is removed and allowed to cool naturally to room temperature. The resulting products are then rinsed multiple times in deionized water and ethanol to remove any soluble impurities. Finally, the product is dried thoroughly in a vacuum oven at 60°C to obtain the 2D nanosheets sample. Furthermore, when combined with N-Heterocyclic Carbenes, Cobalt(II) fluoride tetrahydrate has been found to be highly effective as a catalyst for cross-coupling reactions between aryl Grignard reagents and aryl as well as heteroaryl halides. This reaction results in the formation of unsymmetrical biaryls.

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