PENTAAMMINE(TRIFLUOROMETHANESULFONATO)OSMIUM(III) TRIFLUOROMETHANESULFONATE Chemical Properties

Melting point:

~276 °C (lit.)

form 

powder

InChI

1S/3CHF3O3S.5H3N.Os/c3*2-1(3,4)8(5,6)7;;;;;;/h3*(H,5,6,7);5*1H3;/q;;;;;;;;+3/p-3

InChIKey

HWGAHFXMBKZTPE-UHFFFAOYSA-K

SMILES

N.N.N.N.N.[Os+3].[O-]S(=O)(=O)C(F)(F)F.[O-]S(=O)(=O)C(F)(F)F.[O-]S(=O)(=O)C(F)(F)F

Safety Information

Hazard Codes 

Xi

Risk Statements 

36/37/38

Safety Statements 

26-36

WGK Germany 

3

Storage Class

11 - Combustible Solids

Hazard Classifications

Eye Irrit. 2
Skin Irrit. 2
STOT SE 3

MSDS

• Language:English Provider:SigmaAldrich

PENTAAMMINE(TRIFLUOROMETHANESULFONATO)OSMIUM(III) TRIFLUOROMETHANESULFONATE Usage And Synthesis

Uses

Useful for the dearomatization of anilines, and the stereoselective synthesis of cyclohexanediones by osmium(II)-promoted Michael additions to phenols. Precursor to Fischer carbyne complexes.

reaction suitability

reagent type: catalyst
core: osmium

PENTAAMMINE(TRIFLUOROMETHANESULFONATO)OSMIUM(III) TRIFLUOROMETHANESULFONATE(83781-30-0)Related Product Information

• PENTAAMMINE(TRIFLUOROMETHANESULFONATO)OSMIUM(III) TRIFLUOROMETHANESULFONATE
• AMMONIUM TRIFLUOROMETHANESULFONATE