3-OXO-3-O-TOLYL-PROPIONIC ACID ETHYL ESTER Chemical Properties

Boiling point:

256-257 °C(lit.)

Density 

1.069 g/mL at 25 °C(lit.)

refractive index 

n20/D 1.5255(lit.)

Flash point:

>230 °F

storage temp. 

Sealed in dry,Room Temperature

form 

clear liquid

pka

10.00±0.46(Predicted)

color 

Colorless to Light yellow to Light orange

λmax

287nm(MeOH)(lit.)

CAS DataBase Reference

51725-82-7(CAS DataBase Reference)

Safety Information

WGK Germany 

3

HS Code 

2918.30.3000

MSDS

• Language:English Provider:SigmaAldrich

3-OXO-3-O-TOLYL-PROPIONIC ACID ETHYL ESTER Usage And Synthesis

Uses

Reactant for:• ;Preparation of highly substituted furans by tandem condensation-cyclization reactions using bismuth triflate catalyst1• ;Co/Mn-mediated oxidative cross-coupling2• ;Enantioselective ruthenium-catalyzed hydrogenation3• ;Preparation of cambinol analogs for sirtuin inhibition with antitumor action4

Uses

Reactant for:

• Preparation of highly substituted furans by tandem condensation-cyclization reactions using bismuth triflate catalyst
• Co/Mn-mediated oxidative cross-coupling
• Enantioselective ruthenium-catalyzed hydrogenation
• Preparation of cambinol analogs for sirtuin inhibition with antitumor action

General Description

Ethyl (2-methylbenzoyl)acetate is a β-keto ester. It undergoes Co/Mn mediated oxidative coupling reaction with various indole derivatives.

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