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Hexaethyl tetraphosphate

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Hexaethyl tetraphosphate Basic information

Product Name:
Hexaethyl tetraphosphate
Synonyms:
  • Ethyl tetraphosphate
  • Hexaethyl tetraphosphate
  • Tetraphosphoricacid,hexaethylester
  • HET
  • HTP
  • RCRA waste number P-062
  • diethoxyphosphoryl [diethoxyphosphoryloxy(ethoxy)phosphoryl] ethyl phosphate
  • phosphoric acid diethoxyphosphoryl [diethoxyphosphoryloxy(ethoxy)phosphoryl] ethyl ester
CAS:
757-58-4
MF:
C12H30O13P4
MW:
506.25
EINECS:
212-057-0
Mol File:
757-58-4.mol
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Hexaethyl tetraphosphate Chemical Properties

Melting point:
-40°C
Boiling point:
150°C (rough estimate)
Density 
1.292
refractive index 
1.4273
form 
liquid
EPA Substance Registry System
Hexaethyl tetraphosphate (757-58-4)
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Safety Information

RIDADR 
1611
HazardClass 
6.1(a)
PackingGroup 
II
Hazardous Substances Data
757-58-4(Hazardous Substances Data)
Toxicity
LD50 oral in rabbit: 21mg/kg
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Hexaethyl tetraphosphate Usage And Synthesis

Chemical Properties

Hexaethyl tetraphosphate is a yellow liquid which is miscible with water and many organic solvents except kerosene; hydrolyzes in low concentration; hygroscopic. decomposes at high temperatures. It is difficult to burn. It is toxic by skin absorption and inhalation. It is a mixture of ethyl phosphates and ethyl pyrophosphate. It decomposes at high temperatures. May be found in the form of a dry mixture where the liquid is absorbed onto a dry carrier.

Uses

Hexaethyl tetraphosphate is used as an insecticide, in particular, the insecticide Bladan. The Germans commonly used this chemical as an insecticide during World War II, when nicotine-based insecticides were not available.

Preparation

Hexaethyl tetraphosphate was first synthesised by the German chemist Gerhard Schrader, who reacted phosphorus oxychloride and triethyl orthophosphate at approximately 150 °C. This reaction is known as the Schrader process. The Germans also made hexaethyl tetraphosphate by phosphorus oxychloride and ethyl alcohol. This reaction requires slightly lower pressure than the Schrader process.
The reaction has a chemical equation of POCl3 + 3(C2H5)3PO4 → (C2H5)6P4O13 + 3C2H5Cl.

Definition

A mixture of ethyl phosphates and ethyl pyrophosphates (TEPP).

General Description

Tetraethyl pyrophosphate solid is a solid material on which the phosphate itself is absorbed. The phosphate itself is combustible though Hexaethyl tetraphosphate may take effort to ignite. Hexaethyl tetraphosphate is soluble in water and gradually decomposed by it. Hexaethyl tetraphosphate is toxic by inhalation(dust, etc) and by skin absorption.

Air & Water Reactions

Hexaethyl tetraphosphate is soluble in water and gradually decomposed by it.

Reactivity Profile

Organophosphates are susceptible to formation of highly toxic and flammable phosphine gas in the presence of strong reducing agents such as hydrides. Partial oxidation by oxidizing agents may result in the release of toxic phosphorus oxides.

Hazard

Toxic by ingestion, inhalation, and skin absorption; cholinesterase inhibitor.

Health Hazard

Highly toxic, may be fatal if inhaled, swallowed or absorbed through skin. Contact with molten substance may cause severe burns to skin and eyes. Avoid any skin contact. Effects of contact or inhalation may be delayed. Fire may produce irritating, corrosive and/or toxic gases. Runoff from fire control or dilution water may be corrosive and/or toxic and cause pollution.

Fire Hazard

Combustible material: may burn but does not ignite readily. Containers may explode when heated. Runoff may pollute waterways. Substance may be transported in a molten form.

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