METHYLCYCLOPENTADECENONE
METHYLCYCLOPENTADECENONE Basic information
- Product Name:
- METHYLCYCLOPENTADECENONE
- Synonyms:
-
- 3-methylcyclopentadecenone
- Cyclopentadecenone, 3-methyl-
- Muscenone
- METHYLCYCLOPENTADECENONE
- delta-muscenone
- 2-methylcyclopentadec-2-en-1-one
- CAS:
- 82356-51-2
- MF:
- C16H28O
- MW:
- 236.39292
- EINECS:
- 429-900-5
- Mol File:
- 82356-51-2.mol
METHYLCYCLOPENTADECENONE Chemical Properties
- Density
- 0.927[at 20℃]
- vapor pressure
- 0.04Pa at 25℃
- Odor
- at 10.00 % in dipropylene glycol. musk ketone animal soapy
- Odor Type
- musk
- Water Solubility
- 900μg/L at 20℃
- LogP
- 5.52 at 25℃
METHYLCYCLOPENTADECENONE Usage And Synthesis
Chemical Properties
The main constituents
are (Z)- and (E′)-3-methylcyclopentadec-5-en-1-one. Colorless to light yellow liquid
with a powerful, elegantmusk note reminiscent of nitromusks with a natural
animalic undertone. It is recommended for use in perfume oils for a wide range
of applications, for example, for fine fragrances, for perfuming beauty and fabric
care products, and for perfuming cleaners.
3-Methylcyclopentadecenone is produced by rearrangement of 14-methyl-
16-oxabicyclo[10.3.1]hexadec-1(15)-ene catalyzed by phosphoric acid.
The starting material is obtained by a multistep process starting from cyclododecanone.
Uses
This unsaturated ketone, which yields dl-Muscone upon hydrogenation, has been suggested as a modifier for the related ketones and lactones. It is equally expensive to prepare, and not as natural-musky in its character when compared to l-Muscone.
Flammability and Explosibility
Not classified
Trade name
Muscenone® (Firmenich)
Synthesis
Methylcyclopentadecenone is prepared by cyclization of 2,15 -Diketohexadecane with N-Methylaniline Magnesium bromide reagent.
METHYLCYCLOPENTADECENONESupplier
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