2-BENZYLOXYPHENYLMAGNESIUM BROMIDE, 1M & Chemical Properties

Density 

1.047 g/mL at 25 °C

Flash point:

-20 °C

InChI

1S/C13H11O.BrH.Mg/c1-3-7-12(8-4-1)11-14-13-9-5-2-6-10-13;;/h1-9H,11H2;1H;/q;;+1/p-1

InChIKey

VELKJPFZDYXBDE-UHFFFAOYSA-M

SMILES

Br[Mg]c1ccccc1OCc2ccccc2

Safety Information

Hazard Codes 

F,C

Risk Statements 

11-14/15-19-34-40-37-14

Safety Statements 

16-26-29-33-36/37/39-43-45

RIDADR 

UN 2924 3/PG 2

WGK Germany 

3

HS Code 

2827310000

Storage Class

3 - Flammable liquids

Hazard Classifications

Acute Tox. 4 Oral
Carc. 2
Flam. Liq. 2
Skin Corr. 1B
STOT SE 3

2-BENZYLOXYPHENYLMAGNESIUM BROMIDE, 1M & Usage And Synthesis

Uses

2-Benzyloxyphenylmagnesium bromide can be used:

• As a substrate in the iron-catalyzed coupling reaction of aryl Grignard reagents with unprotected bromophenols.
• As a substrate in the cross-coupling of Grignard reagents using diaryl titanates and ferric chloride.
• In one of the key synthetic steps for the total synthesis of an antibiotic caboxamycin.

reaction suitability

reaction type: Grignard Reaction