Basic information Safety Supplier Related

diethyl methylidenemalonate

Basic information Safety Supplier Related

diethyl methylidenemalonate Basic information

Product Name:
diethyl methylidenemalonate
Synonyms:
  • diethyl methylidenemalonate
  • Diethyl 2-methylenemalonate
  • Diethyl ethylene-1,1-dicarboxylate
  • Diethyl methylenemalonate
  • Methylenemalonic acid diethyl ester
  • Methylenepropanedioic acid diethyl ester
  • Propanedioic acid, 2-Methylene-, 1,3-diethyl ester
  • Propanedioic acid,2-Methylene-, 1,3-diethyl este
CAS:
3377-20-6
MF:
C8H12O4
MW:
172.18
Mol File:
3377-20-6.mol
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diethyl methylidenemalonate Chemical Properties

Melting point:
135.5-136.5 °C(Solv: ethanol (64-17-5))
Boiling point:
210 °C
Density 
1.052 g/cm3(Temp: 25 °C)
storage temp. 
Inert atmosphere,Store in freezer, under -20°C
solubility 
Chloroform (Slightly), Dichloromethane (Slightly)
form 
Oil
color 
Light Yellow
Stability:
Light Sensitive
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Safety Information

Toxicity
mouse,LD,intraperitoneal,> 500mg/kg (500mg/kg),"Summary Tables of Biological Tests," National Research Council Chemical-Biological Coordination Center. Vol. 6, Pg. 147, 1954.
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diethyl methylidenemalonate Usage And Synthesis

Uses

Diethyl 2-methylenemalonate could be a used reagent for synthesizing donor-acceptor cyclobutanes via copper acetate or iron trichloride catalyzed [2+2] cycloaddition.g

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