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Lithium perchlorate trihydrate

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Lithium perchlorate trihydrate Basic information

Product Name:
Lithium perchlorate trihydrate
Synonyms:
  • LITHIUM PERCHLORATE HYDRATE
  • LITHIUM PERCHLORATE TRIHYDRATE
  • Lithium perchlorate trihydrate, extra pure
  • Lithium pechlorate trihydrate
  • Lithium perchlorate trihydrate, extra pure, 99+%
  • LITHIUM PERCHLORATE, TRIHYDRATE (ACS) REAGENT
  • Lithiumperchloratetrihydrate,98%
  • Perchloric acid, lithium salt, trihydrate
CAS:
13453-78-6
MF:
ClH4LiO5
MW:
126.42
EINECS:
680-433-5
Product Categories:
  • Oxidation
  • Perchlorates
  • Synthetic Reagents
  • metal perchlorate salt
Mol File:
13453-78-6.mol
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Lithium perchlorate trihydrate Chemical Properties

Melting point:
95 °C
Boiling point:
decomposes at 470℃ [KIR79]
Density 
1.841 g/mL at 25 °C(lit.)
solubility 
very soluble in H2O, ethanol, acetone;insoluble in ethyl ether
form 
Crystals and/or Chunks
color 
White
Specific Gravity
1.841
Odor
Odorless
Water Solubility 
597 g/L (25 ºC)
Sensitive 
Hygroscopic
Merck 
14,5539
Stability:
hygroscopic
CAS DataBase Reference
13453-78-6(CAS DataBase Reference)
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Safety Information

Hazard Codes 
O,Xi
Risk Statements 
8-36/37/38
Safety Statements 
17-26-27-36/37/39-37/39
RIDADR 
UN 1481 5.1/PG 2
WGK Germany 
1
RTECS 
SC8750000
TSCA 
Yes
HazardClass 
5.1
PackingGroup 
II
HS Code 
28299000

MSDS

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Lithium perchlorate trihydrate Usage And Synthesis

Chemical Properties

White crystal

Uses

Lithium perchlorate trihydrate is used as an oxygen source for chemical oxygen generators as it liberates oxygen at high temperatures. Excellent solubility of lithium perchlorate permits its use in Diels-Alder reactions. It is also employed in lithium-ion batteries as an electrolyte and acts as a chaotropic agent to denature proteins. It is used in the Baylis-Hillman reaction as a catalyst in the coupling of alpha, beta-unsaturated carbonyl compounds with aldehydes.

Uses

Lithium perchlorate trihydrate is used as am oxidizing agent.

General Description

Crystal structure of lithium perchlorate trihydrate (LiClO4.3H2O) has been investigated by X-ray and neutron diffraction studies. It exhibits pyroelectric properties.

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