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ChemicalBook >  Product Catalog >  Organic Chemistry >  Organometallic compounds >  Organic iron >  (S)-(+)-[(R)-2-DICYCLOHEXYLPHOSPHINOFERROCENYL](N,N-DIMETHYLAMINO)(2-DICYCLOHEXYLPHOSPHINOPHENYL)METHANE

(S)-(+)-[(R)-2-DICYCLOHEXYLPHOSPHINOFERROCENYL](N,N-DIMETHYLAMINO)(2-DICYCLOHEXYLPHOSPHINOPHENYL)METHANE

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(S)-(+)-[(R)-2-DICYCLOHEXYLPHOSPHINOFERROCENYL](N,N-DIMETHYLAMINO)(2-DICYCLOHEXYLPHOSPHINOPHENYL)METHANE Basic information

Product Name:
(S)-(+)-[(R)-2-DICYCLOHEXYLPHOSPHINOFERROCENYL](N,N-DIMETHYLAMINO)(2-DICYCLOHEXYLPHOSPHINOPHENYL)METHANE
Synonyms:
  • (S)-(+)-[(R)-2-DICYCLOHEXYLPHOSPHINOFERROCENYL](N,N-DIMETHYLAMINO)(2-DICYCLOHEXYLPHOSPHINOPHENYL)METHANE
  • (SP)-1-Dicyclohexylphosphino-2-[(S)-α-(dimethylamino)-2-(dicyclohexylphosphino)benzyl]ferrocene
  • Taniaphos SL-T002-2, (1R)-1-(Dicyclohexylphosphino)-2-[(S)-[2-(dicyclohexylphosphino)phenyl](dimethylamino)methyl]ferrocene (acc to CAS)
  • (S)-(+)-[(S)-2-Dicyclohexylphosphinoferrocenyl](N,N-dimethylamino)(2- dicyclohexylphosphinophenyl)methane, min. 97%
  • Taniaphos ligand
  • (S)-(+)-[(S)-2-Dicyclohexylphosphinoferrocenyl](N,N-diMethylaMino)(2-dicyclohexylphosphinophenyl)Methane,Min.97%
  • (S)-(-)-[(S)-2-Dicyclohexylphosphinoferrocenyl](N,N-diMethylaMino)(2-dicyclohexylphosphinophenyl)Methane
  • (S)-1-Dicyclohexylphosphino-2-[(S)-a-(N,N-dimethylamino)-o-(dicyclohexylphosphinophenyl)methyl]-ferrocene
CAS:
914089-00-2
MF:
C43H63FeNP210*
MW:
711.76
Product Categories:
  • Chiral Phosphine
  • Ferrocene Series
  • Taniaphos Series
Mol File:
914089-00-2.mol
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(S)-(+)-[(R)-2-DICYCLOHEXYLPHOSPHINOFERROCENYL](N,N-DIMETHYLAMINO)(2-DICYCLOHEXYLPHOSPHINOPHENYL)METHANE Chemical Properties

alpha 
-110° ±10° (c 0.5, CHCl3)
storage temp. 
under inert gas (nitrogen or Argon) at 2-8°C
form 
Powder
color 
orange
Stability:
store cold
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Safety Information

WGK Germany 
3
HS Code 
29319090
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(S)-(+)-[(R)-2-DICYCLOHEXYLPHOSPHINOFERROCENYL](N,N-DIMETHYLAMINO)(2-DICYCLOHEXYLPHOSPHINOPHENYL)METHANE Usage And Synthesis

Reactions

  1. Iron catalyst for olefin cross-coupling
  2. Iron catalyst for regioselective alkylation of diols and polyols.
  3. Ligand for the iridium-catalyzed asymmetric cis hydrogenation of bromobenzothiazepine.

Chemical Properties

Orange powder

General Description

sold in collaboration with Solvias AG

(S)-(+)-[(R)-2-DICYCLOHEXYLPHOSPHINOFERROCENYL](N,N-DIMETHYLAMINO)(2-DICYCLOHEXYLPHOSPHINOPHENYL)METHANESupplier

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