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4CzIPN

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4CzIPN Basic information

Product Name:
4CzIPN
Synonyms:
  • 4CzIPN
  • (4r,6r)-2,4,5,6-tetra(9H-carbazol-9-yl)isophthalonitrile
  • 2,4,5,6-Tetra-9H-carbazol-9-yl-1,3-benzenedicarbonitrile
  • 2,4,5,6-Tetra(9H-carbazol-9-yl)isophthalonitrile
  • 2,4,5,6-tetrakis(carbazol-9-yl)-1,3-dicyanobenzene
  • 1,2,3,5-Tetrakis(carbazol-9-yl)-4,6-dicyanobenzene
  • 1,3-Benzenedicarbonitrile, 2,4,5,6-tetra-9H-carbazol-9-yl-
  • 2,4,5,6-tetrakis(carbazol-9-yl)-1,3-dicyanobenze
CAS:
1416881-52-1
MF:
C56H32N6
MW:
788.89
Product Categories:
  • OLED materrials
  • TADF
Mol File:
1416881-52-1.mol
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4CzIPN Chemical Properties

Density 
1.32±0.1 g/cm3(Predicted)
storage temp. 
Amber Vial, Refrigerator
solubility 
DMSO (Slightly), Methanol (Slightly, Heated, Sonicated)
form 
Solid
color 
Light Yellow to Dark Yellow
Stability:
Light Sensitive
Melting point:
TGA: >300 °C?(0.5% weight loss)
Fluorescene
λem?551 nm in acetonitrile
Absorption
λmax?365 nm in acetonitrile
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4CzIPN Usage And Synthesis

Description

1,2,3,5-Tetrakis(carbazol-9-yl)-4,6-dicyanobenzene (4CzIPN) is a thermally activated delayed fluorescence(TADF)material[1]. And it is a typical donor-acceptor fluorophore, in which carbazolyl is the electron donor and dicyanobenzene is the electron acceptor. Hence,4CzIPN has shown an excellent redox window, good chemical stability and broad applicability. The maximum emission of 4CzIPN in toluene at 507 nm,photoluminescence quantum yield(QY)=94.6%[2]. 4CzIPN can be used as a photocatalyst for organic transformation.

Uses

2,4,5,6-Tetra(9H-carbazol-9-yl)isophthalonitrile is an organic fluorescent dye.

References

[1] Jung Y, et al. A New BODIPY Material for Pure Color and Long Lifetime Red Hyperfluorescence Organic Light-Emitting Diode. ACS Applied Materials Interfaces. 2021; 13: 17882–17891.
[2] Shang T, et al. Recent advances of 1,2,3,5-tetrakis(carbazol-9-yl)-4,6-dicyanobenzene (4CzIPN) in photocatalytic transformations. Chemical Communications. 2019; 55: 5408-5419.

4CzIPNSupplier

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