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(11bS)-4-hydroxy-2,6-bis(2,4,6-tricyclohexylphenyl)-4-oxide-Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin

Basic information Safety Supplier Related

(11bS)-4-hydroxy-2,6-bis(2,4,6-tricyclohexylphenyl)-4-oxide-Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin Basic information

Product Name:
(11bS)-4-hydroxy-2,6-bis(2,4,6-tricyclohexylphenyl)-4-oxide-Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin
Synonyms:
  • (11bS)-4-hydroxy-2,6-bis(2,4,6-tricyclohexylphenyl)-4-oxide-Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin
  • SF110004
  • (11bS )-4-Hydroxy-2,6-bis(2,4,6- tricyclohexylphenyl)-4-oxidedinaphtho[ 2,1-d:1',2'- f][1,3,2]dioxaphosphepin((S )- TCYP)
  • (11bD)-4-Hydroxy-2,6-bis(2,4,6-tricyclohexylphenyl)-4-oxide-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin((S)-TCYP)
  • (S)-4-Hydroxy-2,6-bis(2,4,6-tricyclohexylphenyl)dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepine 4-oxide
  • (11bS)-4-Hydroxy-2,6-bis(2,4,6-tricyclohexylphenyl)-4-oxide-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin, 95%, (99% ee)
  • Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin, 4-hydroxy-2,6-bis(2,4,6-tricyclohexylphenyl)-, 4-oxide, (11bS)-
  • (11bS)-4-Hydroxy-2,6-bis(2,4,6-tricyclohexylphenyl)-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin 4-oxide
CAS:
1309446-14-7
MF:
C68H81O4P
MW:
993.34
Mol File:
1309446-14-7.mol
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(11bS)-4-hydroxy-2,6-bis(2,4,6-tricyclohexylphenyl)-4-oxide-Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin Chemical Properties

Density 
1.22±0.1 g/cm3(Predicted)
refractive index 
n/D
storage temp. 
under inert gas (nitrogen or Argon) at 2-8°C
pka
1.12±0.20(Predicted)
Appearance
White to off-white Solid
InChIKey
RMVWMWZCAKQBAI-UHFFFAOYSA-N || XDXHWHCIFIGZGE-UHFFFAOYSA-N
SMILES
O=P1(O)OC2=C(C=C3C=CC=CC3=C2C4=C(O1)C(=CC=5C=CC=CC54)C=6C(=CC(=CC6C7CCCCC7)C8CCCCC8)C9CCCCC9)C=%10C(=CC(=CC%10C%11CCCCC%11)C%12CCCCC%12)C%13CCCCC%13
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Safety Information

WGK Germany 
WGK 3
Storage Class
11 - Combustible Solids
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(11bS)-4-hydroxy-2,6-bis(2,4,6-tricyclohexylphenyl)-4-oxide-Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin Usage And Synthesis

Uses

(S)-TCYP has been used in asymmetric aza-ene-type reactions, catalyzing the formation of C-C bonds with high levels of diastereoselectivity

(11bS)-4-hydroxy-2,6-bis(2,4,6-tricyclohexylphenyl)-4-oxide-Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepinSupplier

Daicel Chiral Technologies (China)CO.,LTD
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021-50460086-9 15921403865
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Tianjin Derchemist Science & Technology Co., Ltd.
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22-58627059 13920586291
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zdcomcon@126.com
Shanghai Chiral bio-compound co., Ltd.
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021-5068 3667/17749785980/1029026415; 17749785980
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1029026415@qq.com
LaaJoo
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021-60702684 18516024827
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huang.jiayi@sinocompound.com
Greenherbs Science and Technology Development Co., Ltd.
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010-61136123
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