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Rhenium hexafluoride

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Rhenium hexafluoride Basic information

Product Name:
Rhenium hexafluoride
Synonyms:
  • (oc-6-11)-rheniumfluoride(ref6
  • ReF6
  • Rhenium fluoride (ReF6), (OC-6-11)-
  • RHENIUM(VI) FLUORIDE
  • RHENIUM HEXAFLUORIDE
  • RHENIUM FLUORIDE
  • Rhenium hexafluoride 99%
  • Rheniumhexafluoride99%
CAS:
10049-17-9
MF:
F6Re
MW:
300.2
EINECS:
233-172-2
Mol File:
10049-17-9.mol
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Rhenium hexafluoride Chemical Properties

Melting point:
18.8 °C(lit.)
Boiling point:
47.6 °C(lit.)
Density 
6 g/mL at 25 °C(lit.)
vapor pressure 
545 mm Hg ( 25 °C)
solubility 
soluble in HNO 3
form 
yellow liquid or cubic crystals
color 
Yellow
Water Solubility 
soluble HNO3; soluble 1.75mol/1000g anhydrous HF [MER06]
Crystal Structure
Cubic
CAS DataBase Reference
10049-17-9(CAS DataBase Reference)
EPA Substance Registry System
Rhenium fluoride (ReF6), (OC-6-11)- (10049-17-9)
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Safety Information

Hazard Codes 
C
Risk Statements 
14-32-35
Safety Statements 
53-9-23-30-36/37/39-43-45
RIDADR 
UN 3390 6.1/PG 1
WGK Germany 
3
Hazard Note 
Corrosive
HazardClass 
5.1
PackingGroup 
II

MSDS

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Rhenium hexafluoride Usage And Synthesis

Chemical Properties

yellow cub crystal(s); extremely hygroscopic; bluish vapors given off in air; transition point ?1.9 or ?3.45°C; enthalpy of sublimation 32.657kJ/mol (above transition), 41.407 kJ/mol (below transition); enthalpy of fusion 4.635 kJ/mol; enthalpy of vaporization 28.75 kJ/mol; entropy of fusion 60.46 J/(mol·K); entropy of vaporization 93.4J/(mol·K); can be produced by reacting Re powder(s) with F2 at ~100°C; used in the chemical vapor deposition of Re [KIR78] [MER06]

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