BRUCINE SULFATE HYDRATE Chemical Properties

Melting point:

~185 °C (dec.)(lit.)

alpha 

-24 (D/22℃) (c=1, H2O)

storage temp. 

Poison room

form 

Crystals or Fine Crystalline Powder

color 

White to slightly beige

Water Solubility 

Soluble in water.

Sensitive 

Hygroscopic

Merck 

14,1455

BRN 

3875567

InChIKey

DYCXTLLGAUPAQK-YZWZKZGNSA-N

Safety Information

Hazard Codes 

T+

Risk Statements 

26/28-52/53

Safety Statements 

13-45-61

RIDADR 

UN 1544 6.1/PG 2

WGK Germany 

3

HazardClass 

6.1

PackingGroup 

I

HS Code 

29399900

Storage Class

6.1A - Combustible acute toxic Cat. 1 and 2
very toxic hazardous materials

Hazard Classifications

Acute Tox. 2 Inhalation
Acute Tox. 2 Oral
Aquatic Chronic 3

BRUCINE SULFATE HYDRATE Usage And Synthesis

Chemical Properties

white to slightly beige crystals or

Uses

Brucine sulfate hydrate is used as a tool for stereospecific chemical syntheses.

Uses

Brucine sulfate salt hydrate can be used:

• As an electron donor in the synthesis of charge transfer complexes with electron acceptors like DDQ (2,3-dichloro-5,6-dicyano-p-benzoquinone) and chloranilic acid.
• As a chiral agent or chiral dopant in the preparation of lyotropic cholesteric liquid crystalline phases.

General Description

Brucine sulfate hydrate is a sulfate salt of brucine, a major pharmacological constituent of?Strychnos nux-vomica?seeds, that is known for its anti-inflammatory and analgesic activities. Brucine is also used as a chiral resolving agent for the optical resolution of tertiary acetylenic alcohols into enantiomers.

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