MANGANESE(II) CHLORIDE HYDRATE 99.999% Chemical Properties

Melting point:

122 °C(lit.)

Density 

1.913 g/mL at 25 °C(lit.)

storage temp. 

2-8°C

InChI

1S/2ClH.Mn.H2O/h2*1H;;1H2/q;;+2;/p-2

InChIKey

BXRRQHBNBXJZBQ-UHFFFAOYSA-L

SMILES

O.Cl[Mn]Cl

Safety Information

Hazard Codes 

Xn

Risk Statements 

22-36/37/38-52

Safety Statements 

26-36/37-45

WGK Germany 

1

Storage Class

6.1C - Combustible acute toxic Cat.3
toxic compounds or compounds which causing chronic effects

Hazard Classifications

Acute Tox. 3 Oral
Aquatic Chronic 2
Eye Irrit. 2
STOT RE 2

MANGANESE(II) CHLORIDE HYDRATE 99.999% Usage And Synthesis

Uses

Starting material for preparation of organomanganese chloride reagents; Catalyst for reductionof vinyl and aryl halides, stereoselective coupling of vinyl iodides, and alkylation of enol triflates; also used for Mn-Cu-catalyzed conjugate addition of RMgX to enones and for Mn-catalyzed acylation of RMgX by acyl chlorides; in combination with NaBH4 is diastereoselective reducing agent; starting material for the preparation of Mn enolates regio- and stereo-selectively.

reaction suitability

core: manganese
reagent type: catalyst

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