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BIS(3,5-DI-TERT-BUTYL-4-METHOXYPHENYL)CHLOROPHOSPHINE

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BIS(3,5-DI-TERT-BUTYL-4-METHOXYPHENYL)CHLOROPHOSPHINE Basic information

Product Name:
BIS(3,5-DI-TERT-BUTYL-4-METHOXYPHENYL)CHLOROPHOSPHINE
Synonyms:
  • BIS(3,5-DI-TERT-BUTYL-4-METHOXYPHENYL)CHLOROPHOSPHINE
  • BIS(3,5-DI-TERT-BUTYL-4-METHOXYPHENYL)PHOSPHINOUS CHLORIDE
  • Bis(3,5-di-t-butyl-4-methoxyphenyl)chlorophosphine,
  • Bis(3,5-di-t-butyl-4-methoxyphenyl)chlorophosphine,93%
  • Bis[3,5-bis(1,1-dimethylethyl)-4-methoxyphenyl]phosphinous chloride
  • chloro-bis(3,5-ditert-butyl-4-methoxyphenyl)phosphane
  • Phosphinous chloride, P,P-bis[3,5-bis(1,1-dimethylethyl)-4-methoxyphenyl]-
CAS:
212713-08-1
MF:
C30H46ClO2P
MW:
505.11
EINECS:
633-650-4
Product Categories:
  • Catalysis and Inorganic Chemistry
  • Phosphorus Compounds
  • Phosphorus Precursors
Mol File:
212713-08-1.mol
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BIS(3,5-DI-TERT-BUTYL-4-METHOXYPHENYL)CHLOROPHOSPHINE Chemical Properties

Melting point:
116-120 °C
Boiling point:
552.5±50.0 °C(Predicted)
Water Solubility 
Reacts with water.
Sensitive 
Air & Moisture Sensitive
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Safety Information

Hazard Codes 
F
Risk Statements 
11
RIDADR 
UN3261
WGK Germany 
3
HazardClass 
8
PackingGroup 
II
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BIS(3,5-DI-TERT-BUTYL-4-METHOXYPHENYL)CHLOROPHOSPHINE Usage And Synthesis

Uses

It is used as a reactant for asymmetric hydrogenation with iridium catalysts, chemo selective reaction with deprotonated 2-hydoxy-3,3,N-trimethylbutanamide. It is also used as a reactant for synthesis of phosphine- containing amino acids and peptide-based catalyst ligands, nonracemic phosphine-containing amino acids for palladium- catalyzed asymmetric allylic substitution reactions.

BIS(3,5-DI-TERT-BUTYL-4-METHOXYPHENYL)CHLOROPHOSPHINESupplier

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