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ChemicalBook >  Product Catalog >  Pharmaceutical intermediates >  Heterocyclic compound >  Benzo[b]thiophene-3-carbonitrile, 2-amino-4-[(4aS)-8-chloro-10-fluoro-2,3,4,4a,5,6-hexahydro-12-oxo-3-(1-oxo-2-propen-1-yl)-1H,12H-pyrazino[2,1-d][1,5]benzoxazocin-9-yl]-7-fluoro-, (4R)-

Benzo[b]thiophene-3-carbonitrile, 2-amino-4-[(4aS)-8-chloro-10-fluoro-2,3,4,4a,5,6-hexahydro-12-oxo-3-(1-oxo-2-propen-1-yl)-1H,12H-pyrazino[2,1-d][1,5]benzoxazocin-9-yl]-7-fluoro-, (4R)-

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Benzo[b]thiophene-3-carbonitrile, 2-amino-4-[(4aS)-8-chloro-10-fluoro-2,3,4,4a,5,6-hexahydro-12-oxo-3-(1-oxo-2-propen-1-yl)-1H,12H-pyrazino[2,1-d][1,5]benzoxazocin-9-yl]-7-fluoro-, (4R)- Basic information

Product Name:
Benzo[b]thiophene-3-carbonitrile, 2-amino-4-[(4aS)-8-chloro-10-fluoro-2,3,4,4a,5,6-hexahydro-12-oxo-3-(1-oxo-2-propen-1-yl)-1H,12H-pyrazino[2,1-d][1,5]benzoxazocin-9-yl]-7-fluoro-, (4R)-
Synonyms:
  • Benzo[b]thiophene-3-carbonitrile, 2-amino-4-[(4aS)-8-chloro-10-fluoro-2,3,4,4a,5,6-hexahydro-12-oxo-3-(1-oxo-2-propen-1-yl)-1H,12H-pyrazino[2,1-d][1,5]benzoxazocin-9-yl]-7-fluoro-, (4R)-
  • Olomorasib
  • Olomorasib/KRAS G12C inhibitor 19
CAS:
2771246-13-8
MF:
C25H19ClF2N4O3S
MW:
528.96
Mol File:
2771246-13-8.mol
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Benzo[b]thiophene-3-carbonitrile, 2-amino-4-[(4aS)-8-chloro-10-fluoro-2,3,4,4a,5,6-hexahydro-12-oxo-3-(1-oxo-2-propen-1-yl)-1H,12H-pyrazino[2,1-d][1,5]benzoxazocin-9-yl]-7-fluoro-, (4R)- Chemical Properties

Boiling point:
815.8±65.0 °C(Predicted)
Density 
1.56±0.1 g/cm3(Predicted)
pka
-1.15±0.20(Predicted)
form 
Solid
color 
White to off-white
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Benzo[b]thiophene-3-carbonitrile, 2-amino-4-[(4aS)-8-chloro-10-fluoro-2,3,4,4a,5,6-hexahydro-12-oxo-3-(1-oxo-2-propen-1-yl)-1H,12H-pyrazino[2,1-d][1,5]benzoxazocin-9-yl]-7-fluoro-, (4R)- Usage And Synthesis

Uses

Olomorasib is a potent inhibitor of KRAS G12C. Olomorasib significantly inhibits tumor growth (extracted from patent WO2021118877A1)[1].

in vivo

Olomorasib (12.5-100 mg/kg, single dose) inhibits pERK and KRas in mouse models, showing a time- and dose-dependent effect[1].

Animal Model:H358 tumor xenograft mouse model [1]
Dosage:12.5, 25, 50, 100 mg/kg; 30 mg/kg; single dose
Administration:
Result:Exhibited good inhibition of pERK and active KRas after a single dose treatment from 12.5 to 100 mg/kg. 82.2%-90.6 % pERK inhibition, and 73.4%-94% active KRas inhibition were observed at these dose levels.
Showed at 30 mg/kg, 82.6% pERK inhibition observed at 8 hours, and the pERK inhibition decreased to 65.2% at 24 hours. For active KRas, 80.2% inhibition was achieved at 8 hours, and the active KRas inhibition decreased to 54.9% at 24 hours.
Animal Model:Pancreatic Cancer MiaPaca-2 Xenograft Mouse Model[1]
Dosage:5, 10, 30 mg/kg; single dose
Administration:
Result:Showed dose and time dependent inhibition of pERK and active KRas in MiaPaca-2 model.

References

[1] Serge Louis Boulet, et al. Kras g12c inhibitors. Patent WO2021118877A1.

Benzo[b]thiophene-3-carbonitrile, 2-amino-4-[(4aS)-8-chloro-10-fluoro-2,3,4,4a,5,6-hexahydro-12-oxo-3-(1-oxo-2-propen-1-yl)-1H,12H-pyrazino[2,1-d][1,5]benzoxazocin-9-yl]-7-fluoro-, (4R)-Supplier

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