(PENTAFLUOROETHYL)TRIMETHYLSILANE
(PENTAFLUOROETHYL)TRIMETHYLSILANE Basic information
- Product Name:
- (PENTAFLUOROETHYL)TRIMETHYLSILANE
- Synonyms:
-
- (PENTAFLUOROETHYL)TRIMETHYLSILANE
- TRIMETHYLPENTAFLUOROETHYLSILANE
- (Pentafluoroethyl)trimethylsilane 97%
- (Pentafluoroethyl)trimethylsilane97%
- Silane, trimethyl(1,1,2,2,2-pentafluoroethyl)-
- 1,3,6-Trimethyl-2-oxo-2,3-dihydro-1H-benzoimidazole-5-carbaldehyde
- triMethyl(perfluoroethyl)silane
- Pentafluoro(trimethylsilyl)ethane, (Perfluoroethyl)trimethylsilane
- CAS:
- 124898-13-1
- MF:
- C5H9F5Si
- MW:
- 192.2
- Mol File:
- 124898-13-1.mol
(PENTAFLUOROETHYL)TRIMETHYLSILANE Chemical Properties
- Boiling point:
- 60 °C
- Density
- 1.095 g/mL
- refractive index
- 1.3270
- Flash point:
- -17℃
- solubility
- Miscible with tetrahydrofuran.
- form
- liquid
- color
- colorless
- Specific Gravity
- 1.05
- Hydrolytic Sensitivity
- 4: no reaction with water under neutral conditions
- Sensitive
- Moisture Sensitive
- Stability:
- Moisture Sensitive, Volatile
- CAS DataBase Reference
- 124898-13-1(CAS DataBase Reference)
- EPA Substance Registry System
- (Pentafluoroethyl)trimethylsilane (124898-13-1)
Safety Information
- Hazard Codes
- Xi
- Risk Statements
- 11-36/37/38
- Safety Statements
- 26-36/37/39
- RIDADR
- 1993
- Hazard Note
- Irritant
- TSCA
- No
- HazardClass
- 3
- PackingGroup
- II
- HS Code
- 2931900090
(PENTAFLUOROETHYL)TRIMETHYLSILANE Usage And Synthesis
Uses
Silicon-based fluorinating reagents for the efficient trifluoromethylation of carbonyls and ethylene diamines. Precursors used for metal-mediated trifluoromethylation of aromatic, heteroaromatic, vinyl substrates, etc.
Uses
(Pentafluoroethyl)trimethylsilane acts as a silicon-based fluorinating reagent for trifluoromethylation of carbonyls and ethylene diamines. It is also employed as a precursor for metal-mediated trifluoromethylation of aromatic, heteroaromatic and vinyl substrates.
Uses
Trimethylpentafluoroethylsilane ((Pentafluoroethyl)trimethylsilane) may be used as a perfluoroalkylating reagent for the synthesis of the following quinoline derivatives:
- 5-bromo-2-(perfluoroethyl)quinoline
- 8-methoxy-2-(perfluoroethyl)quinoline
- 1-(perfluoroethyl)isoquinoline
- 8-(tert-butoxy)-5,7-dichloro-2-(perfluoroethyl)quinolone
General Description
Trimethylpentafluoroethylsilane ((Pentafluoroethyl)trimethylsilane) is a perfluoroalkylsilane. Alkyl triflates undergo nucleophilic pentafluoroethylation with trimethylpentafluoroethylsilane to form the corresponding pentafluoroethylated alkanes.
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