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Bis(triphenylphosphine)iminium chloride

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Bis(triphenylphosphine)iminium chloride Basic information

Product Name:
Bis(triphenylphosphine)iminium chloride
Synonyms:
  • HEXAPHENYLDIPHOSPHAZENIUM CHLORIDE
  • BIS(TRIPHENYLPHOSPHORANYLIDENE)AMMONIUM CHLORIDE
  • BIS(TRIPHENYLPHOSPHINE)IMINIUM CHLORIDE
  • BIS(TRIPHENYLPHOSPHINE)IMINIUMHLORIDE
  • PPNCI
  • PHOSPHORUS(1+), TRIPHENYL(P,P,P-TRIPHENYLPHOSPHINEIMIDATO-KN)-, CHLORIDE, (T-4)-
  • bis((triphenyl-$l^{5}-phosphanylidene)azanium) dichloride
  • triphenyl-(triphenylphosphoranylideneamino)phosphonium chloride
CAS:
21050-13-5
MF:
C36H30ClNP2
MW:
574.04
EINECS:
244-170-6
Product Categories:
  • Furans ,Coumarins
  • organophosphine ligand
  • Pharmaceutical Intermediates
Mol File:
21050-13-5.mol
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Bis(triphenylphosphine)iminium chloride Chemical Properties

Melting point:
270-272 °C(lit.)
storage temp. 
2-8°C
solubility 
Chloroform (Slightly), Methanol (Slightly)
form 
Powder
color 
white
Water Solubility 
Moderately soluble in water.
BRN 
4097979
CAS DataBase Reference
21050-13-5(CAS DataBase Reference)
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Safety Information

Hazard Codes 
Xi,Xn
Risk Statements 
36/37/38-20
Safety Statements 
26-36-38-36/37/39-22
WGK Germany 
3
10

MSDS

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Bis(triphenylphosphine)iminium chloride Usage And Synthesis

Uses

suzuki reaction

Uses

Co-catalyst used with a chiral Cobalt-salen complex for the asymmetric addition of carbon dioxide to propylene oxide. Also used in the preparation of 5-Hydroxy-clethodim Sulfoxide.

Uses

Bis(triphenylphosphoranylidene)ammonium chloride was used in two-phase titration and electrochemistry, done for physiochemical characterization of sildenafil. It was also used in cyclic voltammetry reactions, used to study ion transfer (IT) and electron transfer (ET), at a liquid-liquid interface supported on a metallic electrode.

General Description

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