(4R,5S)-(+)-4-i-Propyl-5-(3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctyl)-2-oxazolidinone
(4R,5S)-(+)-4-i-Propyl-5-(3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctyl)-2-oxazolidinone Basic information
- Product Name:
- (4R,5S)-(+)-4-i-Propyl-5-(3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctyl)-2-oxazolidinone
- Synonyms:
-
- (4R,5S)-(+)-4-I-PROPYL-5-(3,3,4,4,5,5,6,6,7,7,8,8,8-TRIDECAFLUOROOCTYL)-2-OXAZOLIDINONE,99%
- 2-Oxazolidinone, 4-(1-methylethyl)-5-(3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctyl)-, (4R,5S)-
- (4R,5S)-(+)-4-i-propyl-5-(3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctyl)-2-oxazolidinone
- CAS:
- 1432793-97-9
- MF:
- C14H14F13NO2
- MW:
- 475.25
- Mol File:
- 1432793-97-9.mol
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(4R,5S)-(+)-4-i-Propyl-5-(3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctyl)-2-oxazolidinone Chemical Properties
- Melting point:
- 96-99°C
- alpha
- +46° (c 0.43, CHCl3)
- form
- Powder
- color
- white
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(4R,5S)-(+)-4-i-Propyl-5-(3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctyl)-2-oxazolidinone Usage And Synthesis
Uses
(4R,5S)-(+)-4-i-Propyl-5-(3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctyl)-2-oxazolidinone is a chiral fluorous support for conventional and high-throughput organic synthesis. Induces high stereoselectivity in aldol reactions, cycloadditions, conjugate additions and a variety of other reactions of N-acyl derivatives. The fluorous chain permits rapid and efficient isolation of products by solid phase extraction, using only minimal amounts of common solvents.Class of catalytic ligands which when used with a reducing agent, exhibit enantioselectivity in the reduction of a wide range of substrates.