Basic information Safety Supplier Related

Cerium(IV) Trihydroxide Hydroperoxide

Basic information Safety Supplier Related

Cerium(IV) Trihydroxide Hydroperoxide Basic information

Product Name:
Cerium(IV) Trihydroxide Hydroperoxide
Synonyms:
  • CE(OH)3OOH
  • Cerium hydroxide peroxide (Ce(OH)3(O2H)), (T-4)-
  • tetrahydroxy(oxo)cerium
  • Cerium(IV) Trihydroxide Hydroperoxide
CAS:
93131-81-8
MF:
CeH4O5
MW:
224.14
Mol File:
93131-81-8.mol
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Cerium(IV) Trihydroxide Hydroperoxide Chemical Properties

solubility 
insol H2O, MeCN, EtOH, DMSO, THF.
color 
orange-red solid
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Cerium(IV) Trihydroxide Hydroperoxide Usage And Synthesis

Uses

Used as mild oxidizing reagent for a variety of functional groups.

Synthesis

Cerium(IV) Trihydroxide Hydroperoxide is prepared by the addition of 30% hydrogen peroxide solution (20 mL) to a solution of CeCl3.7H2O (0.03 mol) in water (100 mol). Upon addition of conc NH4OH (15 mL), precipitation of the reagent occurs, which is then washed with water, acetone, and dried in the air (95%).[1]

References

1. Firouzabadi, H.; Iranpoor, N. SC 1984, 14, 875

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