Chloro(triphenylphosphine)gold Chemical Properties

Melting point:

248-249°C

storage temp. 

Keep in dark place,Inert atmosphere,2-8°C

form 

Crystalline Powder

color 

White

Water Solubility 

Soluble in methylene chloride, acetonitrile, benzene and acetone. Insoluble in water and ethanol.

CAS DataBase Reference

14243-64-2(CAS DataBase Reference)

Safety Information

Hazard Codes 

Xi

Risk Statements 

36/37/38-22

Safety Statements 

26-36/37/39-37/39

RIDADR 

3464

WGK Germany 

3

HS Code 

71159010

MSDS

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Chloro(triphenylphosphine)gold Usage And Synthesis

Chemical Properties

White crystalline powder

Uses

Chloro(triphenylphosphine)gold(I) is a common reagent in gold chemistry. It catalyzes certain rearrangement reactions in organic synthesis. It is also used to prepare 1-methylthyminato-N3-triphenylphosphinegold(I) by reacting with 1-methylthymine. It acts as a precursor for the synthesis of gold(I) and gold(III) organometallic compounds.

Uses

Catalyst employed in the cyclization of O-propargyl carbamates to alkylideneoxazolidinones via a 5-exo-digonal pathway at room temperature. Also catalyzes the cycloisomerization of enynes containing a cyclic olefin into highly-fused, polycyclic dienes at room temperature.

Chloro(triphenylphosphine)gold(14243-64-2)Related Product Information

• Triphenylphosphine
• Sodium tetrachloroaurate
• TRIPHENYLPHOSPHINE DIBROMIDE
• Calcium chloride
• Choline chloride
• Bis(triphenylphosphine)palladium(II) chloride
• GOLD CHLORIDE
• Thionyl chloride
• Tris(triphenylphosphine)rhodiu
• Ammonium chloride
• Potassium chloride
• Polyvinyl chloride
• Sodium chloride
• Tetrakis(triphenylphosphine)platinum
• Methylene Chloride
• Difluorochloromethane
• (FORMYLMETHYLENE)TRIPHENYLPHOSPHORANE
• Diphenylphosphine