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METOXURON

Basic information Safety Supplier Related

METOXURON Basic information

Product Name:
METOXURON
Synonyms:
  • 3-(3-Chlor-4-methoxyphenyl)-1,1-dimethylharnstoff
  • 3-(3-chloro-4-methoxyphenyl)-1,1-dimethyl-ure
  • Dosagran
  • Dosanex fl
  • Dosanex mg
  • dosanexfl
  • dosanexmg
  • Herbicide 6602
CAS:
19937-59-8
MF:
C10H13ClN2O2
MW:
228.68
EINECS:
243-433-2
Product Categories:
  • H-MAlphabetic
  • M
  • METI - MZPesticides&Metabolites
  • Pesticides
  • Pesticides&Metabolites
  • Urea structure
  • ACTIVE AGROCHEMICAL INGREDIENTS
  • Plant growth regulatorsPesticides&Metabolites
  • Alpha sort
  • Herbicides
Mol File:
19937-59-8.mol
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METOXURON Chemical Properties

Melting point:
124-127 °C
Boiling point:
391.6±42.0 °C(Predicted)
Density 
1.3100 (rough estimate)
refractive index 
1.5500 (estimate)
Flash point:
2 °C
storage temp. 
APPROX 4°C
solubility 
Chloroform (Slightly), DMSO (Slightly)
pka
13.83±0.70(Predicted)
form 
Solid
color 
White to Off-White
Water Solubility 
678mg/L(23 ºC)
EPA Substance Registry System
Metoxuron (19937-59-8)
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Safety Information

Hazard Codes 
N,Xn,F
Risk Statements 
50/53-36-20/21/22-11
Safety Statements 
60-61-36-26-16-36/37
RIDADR 
UN3077 9/PG 3
RTECS 
YS5775000
Toxicity
mouse,LD50,oral,2542mg/kg (2542mg/kg),ENDOCRINE: OTHER CHANGESBLOOD: OTHER CHANGES,Gigiena i Sanitariya. For English translation, see HYSAAV. Vol. 47(2), Pg. 13, 1982.
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METOXURON Usage And Synthesis

Uses

Metoxuron is used as a herbicide.

Definition

ChEBI: Metoxuron is a member of the class of 3-(3,4-substituted-phenyl)-1,1-dimethylureas that is urea in which one of the nitrogens is substituted by a 3-chloro-4-methoxyphenyl group while the other is substituted by two methyl groups. It is a plant growth regulator and a pre- and post-emergence herbicide used for the control of grasses and broad-leaved weeds in carrots and cereals (e.g. wheat, barley and rye). It has a role as an agrochemical, an environmental contaminant, a herbicide, a xenobiotic, a photosystem-II inhibitor and a plant growth regulator. It is a 3-(3,4-substituted-phenyl)-1,1-dimethylurea, a monomethoxybenzene and a member of monochlorobenzenes.

Metabolic pathway

Photodegradation of metoxuron with UV irradiation in the presence of UV-H2O2 and -TiO2 primarily proceeds with the replacement of the chlorine atom with the hydroxy group and the attack of OH radicals at the 6-position on the phenyl ring. The principal photoproducts identified are 3-(4-methoxy-2,5- paraquinone)-1,1-dimethylurea, hydroxymetoxuron, 3-(3-hydroxy-4-methoxyphenyl)-1,1-dimethylurea, 3-(3-chloro-4-hydroxyphenyl)-1,1-dimethylurea, and 3-(3-chloro-4-methoxyphenyl)-1,1dimethylurea.

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