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1,1'-dioxybiscyclohexan-1-ol

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1,1'-dioxybiscyclohexan-1-ol Basic information

Product Name:
1,1'-dioxybiscyclohexan-1-ol
Synonyms:
  • 1,1'-dioxybiscyclohexan-1-ol
  • Bis-(1-hydroxycyclohexyl)-peroxide
  • cyclohexanone peroxide, <= 91% with >= 9% water
  • cyclohexanone peroxide, <= 32% with >= 68% inert solid
  • cyclohexanone peroxide, <= 72% as a solution, <=9% oxygen
  • cyclohexanone peroxides, <=72% as a paste with <=9% oxygen
  • 1,1'-Dioxybis(cyclohexanol)
  • Cyclohexanol, 1,1'-dioxybis-
CAS:
2407-94-5
MF:
C12H22O4
MW:
230.30068
EINECS:
2193062
Mol File:
2407-94-5.mol
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1,1'-dioxybiscyclohexan-1-ol Chemical Properties

Melting point:
66-68 °C
Boiling point:
444.4°C (rough estimate)
Density 
1.1266 (rough estimate)
refractive index 
1.6000 (estimate)
pka
13.13±0.20(Predicted)
EPA Substance Registry System
Cyclohexanol, 1,1'-dioxybis- (2407-94-5)
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Safety Information

RIDADR 
3105
HazardClass 
5.2
PackingGroup 
II
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1,1'-dioxybiscyclohexan-1-ol Usage And Synthesis

Reactivity Profile

The explosive instability of the lower dialkyl peroxides (e.g., dimethyl peroxide) and 1,1-bis-peroxides decreases rapidly with increasing chain length and degree of branching, the di-tert-alkyl derivatives being amongst the most stable class of peroxides. Though many 1,1-bis-peroxides have been reported, few have been purified because of the higher explosion hazards compared with the monofunctional peroxides. 1,1'-dioxybiscyclohexan-1-ol is unlikely that this derivative would be particularly unstable compared to other peroxides in it's class, Bretherick 2nd ed., p 44 1979. Very temperature and shock sensitive.

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