ChemicalBook > Product Catalog > Organic Chemistry > Organometallic compounds > Naphthalene, radical ion(1-), lithium (1:1)
Naphthalene, radical ion(1-), lithium (1:1)
Naphthalene, radical ion(1-), lithium (1:1) Basic information
- Product Name:
- Naphthalene, radical ion(1-), lithium (1:1)
- Synonyms:
-
- Naphthalene, radical ion(1-), lithium (1:1)
- Lithium naphthylide
- Copper(I) Iodide-Triethylphosphine-Lithium Naphthalenide
- CAS:
- 7308-67-0
- MF:
- C10H8Li+
- MW:
- 135.11
- Mol File:
- 7308-67-0.mol
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Naphthalene, radical ion(1-), lithium (1:1) Usage And Synthesis
Chemical Properties
Copper species generated in THF, dioxane, glyme, etc. The reagent is generated in an inert atmosphere as needed.
Uses
Naphthalene, radical ion(1-), lithium (1:1) is a zerovalent copper species which adds to organic halides to produce organocopper compounds; used to cross-couple aryl, alkynyl, and vinyl halides with acid chlorides and reactive alkyl halides; to effect conjugate additions to α,β-unsaturated ketones; to promote intramolecular cyclization with epoxide cleavage or of α,ο-dihaloalkanes; to remotely functionalize esters.