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BOC-THIONOPHE-1-(6-NITRO)BENZOTRIAZOLIDE

Product Name
BOC-THIONOPHE-1-(6-NITRO)BENZOTRIAZOLIDE
CAS No.
184951-87-9
Chemical Name
BOC-THIONOPHE-1-(6-NITRO)BENZOTRIAZOLIDE
Synonyms
BOC-THIONOPHE-1-(6-NITRO)BENZOTRIAZOLIDE;(S)-2-(Boc-amino)-3-phenyl propanethioic O-acid-1-;(S)-2-(BOC-AMINO)-PRPPNETHIOIC O-ACID-1-(6-NITRO)BENZOTRIAZOLIDE;BOC-L-2-AMINO-3-PHENYLPROPANETHIOIC ACID-1-(6-NITRO)BENZOTRIAZOLIDE;(S)-2-(BOC-AMINO)-3-PHENYL-PROPANETHIOIC O-ACID-1-(6-NITRO)BENZOTRIAZOLIDE;(S)-2-[(t-Butoxycarbonyl)amino]-1-(6-nitrobenzotriazol-1-yl)-3-phenylpropane-1-thione;N-ALPHA-T-BUTOXYCARBONYL-L-2-AMINO-3-PHENYLPROPANETHIOIC ACID-1-(6-NITRO) BENZOTRIAZOLIDE;tert-butyl N-[(2S)-1-(6-nitrobenzotriazol-1-yl)-3-phenyl-1-sulfanylidenepropan-2-yl]carbamate;[(1S)-2-(6-Nitro-1H-benzotriazol-1-yl)-1-(phenylmethyl)-2-thioxoethyl]carbamic acid tert-butyl ester;Carbamic acid, [(1S)-2-(6-nitro-1H-benzotriazol-1-yl)-1-(phenylmethyl)-2-thioxoethyl]-, 1,1-dimethylethyl ester (9CI)
CBNumber
CB0753852
Molecular Formula
C20H21N5O4S
Formula Weight
427.48
MOL File
184951-87-9.mol
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BOC-THIONOPHE-1-(6-NITRO)BENZOTRIAZOLIDE Property

Density 
1.36
storage temp. 
-15°C
pka
10.06±0.46(Predicted)
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Hazard and Precautionary Statements (GHS)

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N-Bromosuccinimide Price

Biosynth Carbosynth
Product number
FB111268
Product name
Boc-Thionophe-1-(6-nitro)benzotriazolide
Packaging
250mg
Price
$150
Updated
2021/12/16
Biosynth Carbosynth
Product number
FB111268
Product name
Boc-Thionophe-1-(6-nitro)benzotriazolide
Packaging
500mg
Price
$260
Updated
2021/12/16
Biosynth Carbosynth
Product number
FB111268
Product name
Boc-Thionophe-1-(6-nitro)benzotriazolide
Packaging
1g
Price
$453
Updated
2021/12/16
American Custom Chemicals Corporation
Product number
CCH0007944
Product name
(S)-2-(BOC-AMINO)-3-PHENYL PROPANETHIOIC O-ACID-1-(6-NITRO)BENZOTRIAZOLIDE
Purity
95.00%
Packaging
5MG
Price
$497.43
Updated
2021/12/16
AK Scientific
Product number
0001CS
Product name
Boc-ThionoPhe-1-(6-nitro)benzotriazolide
Packaging
1g
Price
$661
Updated
2021/12/16
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BOC-THIONOPHE-1-(6-NITRO)BENZOTRIAZOLIDE Chemical Properties,Usage,Production

Uses

BOC-THIONOPHE-1-(6-NITRO)BENZOTRIAZOLIDE can be used as organic synthesis intermediate and pharmaceutical intermediate, mainly used in laboratory research and development process and chemical production process.

Synthesis


To a solution of thioanilide 7 (2 mmol) dissolved by gentle warming at 40 °C and then cooled to 0 °C in glacial acetic acid (diluted with 5% water, 15 mL) was added NaNO2 (0.21 g, 3 mmol) in portions over 5 min with stirring. After 30 min, ice water (~100 mL) was added, and the precipitated product was filtered and washed with water. The orange solid was dried in vacuo at rt overnight and then at 50 °C for 4 h to afford benzotriazoles 1-(N-BOC-L-thionophenylalaninyl)-6-nitrobenzotriazole (9b): yield 81%. as amorphous solids of sufficient purity for use in the next step.

BOC-THIONOPHE-1-(6-NITRO)BENZOTRIAZOLIDE Preparation Products And Raw materials

Raw materials

Preparation Products

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BOC-THIONOPHE-1-(6-NITRO)BENZOTRIAZOLIDE Suppliers

Watanabe Chemical Industries, Ltd.
Tel
--
Fax
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Country
Japan
ProdList
4813
Advantage
42
Watanabe Chemical Industries, Ltd.
Tel
--
Fax
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Email
inquiry@watanabechem.co.jp
Country
Japan
ProdList
1920
Advantage
50

184951-87-9, BOC-THIONOPHE-1-(6-NITRO)BENZOTRIAZOLIDERelated Search:


  • (S)-2-(BOC-AMINO)-3-PHENYL-PROPANETHIOIC O-ACID-1-(6-NITRO)BENZOTRIAZOLIDE
  • (S)-2-(BOC-AMINO)-PRPPNETHIOIC O-ACID-1-(6-NITRO)BENZOTRIAZOLIDE
  • N-ALPHA-T-BUTOXYCARBONYL-L-2-AMINO-3-PHENYLPROPANETHIOIC ACID-1-(6-NITRO) BENZOTRIAZOLIDE
  • (S)-2-(Boc-amino)-3-phenyl propanethioic O-acid-1-
  • BOC-THIONOPHE-1-(6-NITRO)BENZOTRIAZOLIDE
  • BOC-L-2-AMINO-3-PHENYLPROPANETHIOIC ACID-1-(6-NITRO)BENZOTRIAZOLIDE
  • [(1S)-2-(6-Nitro-1H-benzotriazol-1-yl)-1-(phenylmethyl)-2-thioxoethyl]carbamic acid tert-butyl ester
  • Carbamic acid, [(1S)-2-(6-nitro-1H-benzotriazol-1-yl)-1-(phenylmethyl)-2-thioxoethyl]-, 1,1-dimethylethyl ester (9CI)
  • (S)-2-[(t-Butoxycarbonyl)amino]-1-(6-nitrobenzotriazol-1-yl)-3-phenylpropane-1-thione
  • tert-butyl N-[(2S)-1-(6-nitrobenzotriazol-1-yl)-3-phenyl-1-sulfanylidenepropan-2-yl]carbamate
  • 184951-87-9
  • C20H21N5O4S