TRIMETHYLENE DI(THIOTOSYLATE)

Product Name: TRIMETHYLENE DI(THIOTOSYLATE)
CAS No.: 3866-79-3
Chemical Name: TRIMETHYLENE DI(THIOTOSYLATE)
Synonyms: NSC 82472;1,3-DI(P-TOSYLTHIO)PROPANE;TRIMETHYLENE DI(THIOTOSYLATE);1,3-Propanedithiol ditosylate;1,3-PROPANEDIYL DI(THIOTOSYLATE);1,3-Propanediylbis(tosyl sulfide);1,3-bis(p-toluenesulfonylthio)propane;Trimethylene di-p-toluenethiosulfonate;TRIMETHYLENE BIS(P-TOLUENETHIOSULFONATE);1,3-Propanedithiolebis(p-toluenesulfonate)
CBNumber: CB0100135
Molecular Formula: C17H20O4S4
Formula Weight: 416.58
MOL File: 3866-79-3.mol

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TRIMETHYLENE DI(THIOTOSYLATE) Property

Melting point:: 64-67 °C
Boiling point:: 592.3±60.0 °C(Predicted)
Density: 1.340±0.06 g/cm3(Predicted)
form: powder to crystal
color: White to Almost white
BRN: 2020157
CAS DataBase Reference: 3866-79-3

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Safety

Safety Statements: 22-24/25
WGK Germany: 3
HS Code: 2930.90.2900

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

TCI Chemical

Product number: D2390
Product name: Trimethylene Di(thiotosylate) [Protecting Reagent for Active Methylene]
Purity: >95.0%(HPLC)
Packaging: 5g
Price: $65
Updated: 2024/03/01

TCI Chemical

Product number: D2390
Product name: Trimethylene Di(thiotosylate) [Protecting Reagent for Active Methylene]
Purity: >95.0%(HPLC)
Packaging: 25g
Price: $197
Updated: 2024/03/01

TRC

Product number: T796183
Product name: TrimethyleneDi(thiotosylate)
Packaging: 2.5g
Price: $85
Updated: 2021/12/16

AK Scientific

Product number: 9310AL
Product name: Trimethylenedi(thiotosylate)
Packaging: 5g
Price: $149
Updated: 2021/12/16

Chem-Impex

Product number: 37319
Product name: S,S-Trimethylenedi(p-toluenethiosulfonate),≥95%(HPLC)
Purity: ≥95%(HPLC)
Packaging: 5G
Price: $75.71
Updated: 2021/12/16

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TRIMETHYLENE DI(THIOTOSYLATE) Chemical Properties,Usage,Production

Uses

Trimethylene Di(thiotosylate) is used as a reactant in the enantioselective total synthesis of (-)-O-methylpallidinine, which is a naturally occurring morphinan alkaloid.

Reactions

1,3-Propanedithiol Bis(p-toluenesulfonate) could be used in the below reactions:
dithianylation and dithiolanylation of methylene groups adjacent to carbonyl; α,α-dithianyl cycloalkanones undergo oxidative ring scission; oxidation of ketones to 1,2-diketones can be achieved by α,α-dithianylation or dithiolanation of ketones followed by hydrolysis.

Synthesis

Treatment of potassium thiotosylate, itself made by the reaction of p-Toluenesulfonyl Chloride with Potassium Hydrogen Sulfide, with 1,3-dibromopropane or 1,2-dibromoethane in the presence of Potassium Iodide affords 1,3-propanedithiol bis(p-toluenesulfonate) and 1,2-ethanedithiol bis(p-toluenesulfonate), respectively.

TRIMETHYLENE DI(THIOTOSYLATE) Preparation Products And Raw materials

Raw materials

Preparation Products

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TRIMETHYLENE DI(THIOTOSYLATE) Suppliers

Americas 1 China 51 Europe 1 Germany 2 India 2 Japan 1 Switzerland 1 United Kingdom 2 United States 7 Global 68

J & K SCIENTIFIC LTD.

Tel: 010-82848833 400-666-7788
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Tel: 021-61259108 18621169109
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3B Pharmachem (Wuhan) International Co.,Ltd.

Tel: 821-50328103-801 18930552037
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TCI (Shanghai) Development Co., Ltd.

Tel: 021-67121386
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Email: Sales-CN@TCIchemicals.com
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Shanghai Hanhong Scientific Co.,Ltd.

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Chengdu Ai Keda Chemical Technology Co., Ltd.

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Shanghai civi chemical technology co.,Ltd

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TOKYO CHEMICAL INDUSTRY CO., LTD.

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TCI Europe

Tel: 320-37350700
Fax: +32 (0)37350701
Email: sales@tcieurope.eu
Country: Europe
ProdList: 23671
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View Lastest Price from TRIMETHYLENE DI(THIOTOSYLATE) manufacturers

Hebei Weibang Biotechnology Co., Ltd

Product: TRIMETHYLENE DI(THIOTOSYLATE) 3866-79-3
Price: US $0.00-0.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 20 mt
Release date: 2024-12-10

Shaanxi Dideu Medichem Co. Ltd

Product: TRIMETHYLENE DI(THIOTOSYLATE) 3866-79-3
Price: US $1.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 20T
Release date: 2024-08-14

Hebei Mujin Biotechnology Co.,Ltd

Product: TRIMETHYLENE DI(THIOTOSYLATE) 3866-79-3
Price: US $0.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 50000KG/month
Release date: 2023-08-17

3866-79-3, TRIMETHYLENE DI(THIOTOSYLATE)Related Search:

Styrene Methyl propyl disulfide methyl methanethiosulfinate Propyl Methanethiosulfonate S-METHYL 4-METHYLBENZENETHIOSULFONATE TRIMETHYLENE DI(THIOTOSYLATE) 1,3-Propanediyl Bismethanethiosulfonate ETHYL METHANETHIOSULFONATE S-Methyl methanethiolsulfonate METHYL PHENYL DISULFIDE PHENYLETHYLDISULFIDE 1,3-Dimercaptopropane

1,3-DI(P-TOSYLTHIO)PROPANE

1,3-PROPANEDIYL DI(THIOTOSYLATE)

TRIMETHYLENE BIS(P-TOLUENETHIOSULFONATE)

TRIMETHYLENE DI(THIOTOSYLATE)

Trimethylene Di(thiotosylate) [Protecting Reagent for Active Methylene]

S,S'-Trimethylene di(p-toluenethiosulfonate)

Benzenesulfonothioic acid, 4-methyl-, S,S-1,3-propanediyl ester

1,3-Di(p-tosylthio)propane, 1,3-Propanediyl di(thiotosylate), Trimethylene di(thiotosylate)

1,3-Propanedithiolebis(p-toluenesulfonate)

1,3-Propanediylbis(tosyl sulfide)

p-Toluenesulfonothioic acid S-[3-[(4-methylphenyl)sulfonylthio]propyl] ester

NSC 82472

Trimethylene di-p-toluenethiosulfonate

Benzenesulfonothioicacid, 4-methyl-, S1,S1'-1,3-propanediyl ester

1,3-Di(p-tosylthio)propane 1,3-Propanediyl Di(thiotosylate) Trimethylene Bis(p-toluenethiosulfonate)

1-methyl-4-[3-(4-methylphenyl)sulfonylsulfanylpropylsulfanylsulfonyl]benzene

1-methyl-4-[3-[(4-methylphenyl)sulfonylthio]propylthio]sulfonyl-benzene

1,3-Bis(4-methylbenzenesulfonylthio)propane

1,3-Propanedithiol ditosylate

4-Methylbenzenesulfonothioic acid S1,S1'-1,3-propanediyl ester

1,3-bis(p-toluenesulfonylthio)propane

TrimethyleneDi(thiotosylate)[ProtectingReagentforActiveMethylene]&gt

S,S'-Trimethylene di(p-toluenethiosulfonate)

3866-79-3

CH3C6H4SO2SCH2CH2CH2SSO2C6H4CH3

C17H20O4S4

Protection & Derivatization Reagents (for Synthesis)

Sulfur Compounds (for Synthesis)

Building Blocks

Organic Building Blocks

Sulfur Compounds

Tosylates

Building Blocks

Chemical Synthesis

Organic Building Blocks

Sulfur Compounds

Tosylates

Synthetic Organic Chemistry

Protection & Derivatization Reagents (for Synthesis)

Sulfur Compounds (for Synthesis)

blocks

BuildingBlocks