S-Methyl methanethiolsulfonate

Product Name: S-Methyl methanethiolsulfonate
CAS No.: 2949-92-0
Chemical Name: S-Methyl methanethiolsulfonate
Synonyms: S-Methyl methanesulfonothioate;METHYL METHANETHIOLSULFONATE;S-METHYL METHANETHIOSULFONATE;METHYL METHANETHIOSULFONATE;S-METHYL METHANETHIOSULPHONATE;(methanesulfonylsulfanyl)methane;NSC 21545;dimethyl thiosulfonate;Neticonazole Impurity 14;Methanethiosulfonylmethyl
CBNumber: CB0331614
Molecular Formula: C2H6O2S2
Formula Weight: 126.2
MOL File: 2949-92-0.mol

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S-Methyl methanethiolsulfonate Property

Melting point:: 117.0-119.0 °C
Boiling point:: 69-71 °C0.4 mm Hg(lit.)
Density: 1.337 g/mL at 25 °C(lit.)
refractive index: n20/D 1.513(lit.)
Flash point:: 190 °F
storage temp.: 2-8°C
solubility: chloroform: soluble750mg + 5 ml Chloroformmg/mL, colorless to light greenish-yellow
form: clear liquid
color: Colorless to Red to Green
Odor: at 0.10 % in propylene glycol. sulfurous pungent roasted
Odor Type: sulfurous
BRN: 1446059
Stability:: Water Sensitive
InChIKey: XYONNSVDNIRXKZ-UHFFFAOYSA-N
LogP: 0.247 (est)
CAS DataBase Reference: 2949-92-0(CAS DataBase Reference)
NIST Chemistry Reference: S-methyl methanethiosulphonate(2949-92-0)
EPA Substance Registry System: Methanesulfonothioic acid, S-methyl ester (2949-92-0)

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Safety

Hazard Codes: Xi,Xn
Risk Statements: 36-36/37/38-20/21/22
Safety Statements: 26-36/37/39
RIDADR: 3334
WGK Germany: 2
RTECS: PB2765000
F: 13
HazardClass: IRRITANT
PackingGroup: III
HS Code: 29309090
Toxicity: mouse,LD50,intraperitoneal,9110ug/kg (9.11mg/kg),Toxicology and Applied Pharmacology. Vol. 72, Pg. 513, 1984.

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H227Combustible liquid

H315Causes skin irritation

H319Causes serious eye irritation

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P270Do not eat, drink or smoke when using this product.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P403+P233Store in a well-ventilated place. Keep container tightly closed.

P405Store locked up.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 208795
Product name: S-Methyl methanethiosulfonate
Purity: 97%
Packaging: 1g
Price: $42.7
Updated: 2024/03/01

Sigma-Aldrich

Product number: 208795
Product name: S-Methyl methanethiosulfonate
Purity: 97%
Packaging: 10g
Price: $232
Updated: 2024/03/01

TCI Chemical

Product number: M1382
Product name: S-Methyl Methanethiosulfonate
Purity: >97.0%(GC)
Packaging: 5g
Price: $76
Updated: 2024/03/01

TCI Chemical

Product number: M1382
Product name: S-Methyl Methanethiosulfonate
Purity: >97.0%(GC)
Packaging: 25g
Price: $249
Updated: 2024/03/01

Sigma-Aldrich

Product number: 64306
Product name: S-Methyl methanethiosulfonate
Purity: purum, ≥98.0% (GC)
Packaging: 1ml
Price: $45.7
Updated: 2024/03/01

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S-Methyl methanethiolsulfonate Chemical Properties,Usage,Production

Chemical Properties

Light Yellow Liquid

Uses

carbonyl reactive homobifunctional cross-linking reagent cleavable with periodate

Uses

S-Methyl methanethiosulfonate was used as sulfenylating agent for β-keto sulfoxides, methylene compounds, half-esters of malonic acids and aryl Grignard reagents. It was also used as a reagent to trap the natural thiol-disulfide state of the proteins.

Uses

S-Methyl methanethiolsulfonate is used for the rapid and selective modification of sulfhydryl groups of enzymes and it is also useful for mapping the pore-lining regions of the ryanodine receptor.

Definition

ChEBI: A sulfonic acid derivative obtained by condensaton of methanesulfonic acid with methanethiol.

Synthesis Reference(s)

The Journal of Organic Chemistry, 49, p. 2281, 1984 DOI: 10.1021/jo00186a039
Synthetic Communications, 20, p. 365, 1990 DOI: 10.1080/00397919008052777

General Description

Interaction of S-methyl methanethiosulfonate (MMTS) with dipalmitoylphosphatidylcholine (DPPC) bilayers has been investigated by FTIR and surface-enhanced Raman spectroscopy.

Purification Methods

Purify it by fractional distillation under reduced pressure, IR: 1350, 750 cm-1 . [Applegate et al. J Org Chem 38 943 1973, Beilstein 4 IV 31.]

S-Methyl methanethiolsulfonate Preparation Products And Raw materials

Raw materials

Preparation Products

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S-Methyl methanethiolsulfonate Suppliers

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View Lastest Price from S-Methyl methanethiolsulfonate manufacturers

Xian confluore Biological Technology Co., Ltd.

Product: MMTS [Methyl methanethiolsulfonate] 2949-92-0
Price: US $0.00/g
Min. Order: 100g
Purity: >95.00%
Supply Ability: 100g
Release date: 2024-04-01

Zhuozhou Wenxi import and Export Co., Ltd

Product: S-Methyl methanethiolsulfonate 2949-92-0
Price: US $15.00-10.00/KG
Min. Order: 1KG
Purity: 99%+ HPLC
Supply Ability: Monthly supply of 1 ton
Release date: 2021-08-11

Career Henan Chemical Co

Product: S-Methyl methanethiolsulfonate 2949-92-0
Price: US $5.50/KG
Min. Order: 1KG
Purity: 98%min
Supply Ability: 1kg-100kg
Release date: 2020-01-09

2949-92-0, S-Methyl methanethiolsulfonateRelated Search:

Kresoxim-methyl Methanesulfonic acid Methanol p-Toluenesulfonic acid Methyl methanesulfonate Basic Violet 1 Methylparaben Methyl methacrylate Methyl p-toluenesulfonate Acetonitrile Methyl acrylate Methyl acetate Paraquat dichloride 2-METHYL-2-PROPENE-1-SULFONIC ACID SODIUM SALT Ethyl methanesulfonate methyl methanethiosulfinate Dimethyl disulfide 2,2'-BIPYRIDINE-4-CARBALDEHYDE

S-Methyl thiomethanesuphonate

4-methyl-2-amino-1,3-thiazole

Methanethiosulfonylmethyl

Methyl(methylsulfonyl) sulfide

Methyl(methylthio) sulfone

S-Methyl methanethiolsulfonate,97%

5-METHYLMETHANETHIONSULFONATE

NSC 21545

ThioMethanesulfonic Acid S-Methyl Ester

Methyl Methanothiosulfonate

S-Methyl methanesulphonothioate

S-Methyl methanethiosulfonate,S-Methyl thiomethanesulfonate, MMTS

S-Methyl Methanethiosulfonate 97%

S-Methyl Methanethiosulfonate puruM, >=98.0% (GC)

(methanesulfonylsulfanyl)methane

S-METHYL THIOMETHANESULFONATE

S-METHYL METHANETHIOLSULFONATE

S-METHYL METHANETHIONSULFONATE

S-METHYL METHANETHIOSULFONATE

S-METHYL METHANETHIOSULPHONATE

dimethyl thiosulfonate

Methanesulfonic acid, thio-, S-methyl ester

Methanesulfonothioic acid, S-methyl ester

methanesulfonothioicacid,s-methylester

Methyl methanesulfonothioate

methylmethanesulfonothioate

S-Methyl methanesulfonothioate

S-methyl methylthiosulfonate

s-methylmethanesulfonothioate

thio-methanesulfonicacis-methylester

S-Methylemethanethiolsulfonate

METHYL METHANETHIOLSULFONATE

METHYL METHANETHIOSULFONATE

METHANETHIOSULFONIC ACID S-METHYL ESTER

S-Methylmethanthiosulfonat

S-MethylMethanethiosulfonate&gt

Neticonazole Impurity 14

MMTS [Methyl methanethiolsulfonate

2949-92-0

C2H6O2S2

C2H6S2O2

CH3SO2SCH3

Sulfonates/Sulfinates

Sulfur Compounds

Organic Building Blocks

Sulfur Compounds (for Synthesis)

Building Blocks

Small molecule

MTS and Sulfhydryl Active Reagents

Sulfur Compounds (for Synthesis)

Synthetic Organic Chemistry

MTS & Sulfhydryl Active Reagents