Chromic sulfate Property

Density 

3.012

solubility 

soluble in H2O; very soluble in acid solutions

form 

Crystalline

color 

red

Water Solubility 

insoluble H2O, acids [MER06]

Stability:

Stable.

CAS DataBase Reference

10101-53-8(CAS DataBase Reference)

EPA Substance Registry System

Chromium(III) sulfate (10101-53-8)

Safety

RIDADR 

UN 9100

Hazardous Substances Data

10101-53-8(Hazardous Substances Data)

Toxicity

MLD in frogs, mice, rabbits (mg/kg): 37, 246.8, 215 i.v. (Cavalli)

Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H290May be corrosive to metals

H302Harmful if swallowed

H315Causes skin irritation

H317May cause an allergic skin reaction

H319Causes serious eye irritation

H332Harmful if inhaled

H411Toxic to aquatic life with long lasting effects

Precautionary statements

P234Keep only in original container.

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P270Do not eat, drink or smoke when using this product.

P271Use only outdoors or in a well-ventilated area.

P272Contaminated work clothing should not be allowed out of the workplace.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P312Call a POISON CENTER or doctor/physician if you feel unwell.

P321Specific treatment (see … on this label).

P330Rinse mouth.

P332+P313IF SKIN irritation occurs: Get medical advice/attention.

P333+P313IF SKIN irritation or rash occurs: Get medical advice/attention.

P362Take off contaminated clothing and wash before reuse.

P363Wash contaminated clothing before reuse.

P390Absorb spillage to prevent material damage.

P404Store in a closed container.

P501Dispose of contents/container to..…

Chromic sulfate Chemical Properties,Usage,Production

Physical Properties

Reddish-brown hexagonal crystal; the pentadecahydrate is a dark green amorphous substance while the octadecahydrate is a violet cubic crystal; the densities are 3.10 g/cm3 (the anhydrous salt), 1.87 g/cm3 (pentadecahydrate), 1.709/cm3 (octadecahydrate); the anhydrous sulfate is insoluble in water and acids; the hydrate salts are soluble in water; the pentadecahydrate is insoluble in alcohol, but the octadecahydrate dissolves in alcohol.

Uses

Chromium(III) sulfate is used as the electrolyte for obtaining pure chromium metal. It is used for chrome plating of other metals for protective and decorative purposes. Other important applications of this compound are as a mordant in the textile industry; in tanning leather; to dissolve gelatin; to impart green color to paints, varnishes, inks, and ceramic glazes; and as a catalyst.

Preparation

Chromium(III) sulfate is prepared by treating chromium(III) hydroxide with sulfuric acid followed by crystallization:
2Cr(OH)3 + 3H2SO4 → Cr2(SO4)3 + 6H2O

Description

Chromic sulfate is a peach-colored solid or redto violet, odorless powder. Molecular weight =392.18.Hazard Identification (based on NFPA-704 M RatingSystem): Health 1, Flammability 0, Reactivity 0. Insolublein water

Chemical Properties

Also known as chromic sulfate,Cr2(S04)3, is a violet or red powder that is insoluble in water and acids.The basic form (reduction of sodium dichromate) is used in tanning. Other uses are chrome plating,chromium alloys,mordant,catalyst,green paints and varnishes,green ink,and ceramic glazes.

Chemical Properties

Chromic sulfate is a peach colored solid or red to violet, odorless powder.

Uses

Chrome plating, chromium alloys, mordant, catalyst, green paints and varnishes, green ink, ceramics (glazes). The basic form (reduction of sodium dichromate) is used in tanning.

Definition

ChEBI: A compound of chromium and sulfate in which the ratio of chromium (in the +3 oxidation state) to sulfate is 2:3

General Description

Dark green to violet crystalline material. Used in paints and inks, ceramics, and in textile dyeing. I Chromic sulfate is noncombustible. The primary hazard of Chromic sulfate is the potential for environmental damage if released. Immediate steps should be taken to limit its spread to the environment.

Air & Water Reactions

Water soluble.

Reactivity Profile

Chromic sulfate has weak oxidizing or reducing powers. Redox reactions can however still occur. The majority of compounds in this class are slightly soluble or insoluble in water. If soluble in water, then the solutions are usually neither strongly acidic nor strongly basic. These compounds are not water-reactive.

Health Hazard

INHALATION: Corrosive action on mucous membranes. SKIN: May elicit an allergic reaction. Corrosive action on skin. Lesions confined to exposed parts.

Fire Hazard

Special Hazards of Combustion Products: Decomposes to chromic acid when heated.

Potential Exposure

This compound is used in green paints, inks, dyes, and ceramics

First aid

If this chemical gets into the eyes, remove anycontact lenses at once and irrigate immediately for at least15 min, occasionally lifting upper and lower lids. Seek medical attention immediately. If this chemical contacts theskin, remove contaminated clothing and wash immediatelywith soap and water. Seek medical attention immediately. Ifthis chemical has been inhaled, remove from exposure,begin rescue breathing (using universal precautions, including resuscitation mask) if breathing has stopped and CPR ifheart action has stopped. Transfer promptly to a medicalfacility. When this chemical has been swallowed, get medical attention. Give large quantities of water and inducevomiting. Do not make an unconscious person vomit

storage

Color Code—Green: General storage may be used.Prior to working with chromic sulfate you should be trainedon its proper handling and storage. Store in tightly closedcontainers in a cool, well-ventilated area away from strongoxidizers and sources of heat.

Shipping

UN3077 Environmentally hazardous substances, solid, n.o.s., Hazard class: 9; Labels: 9-Miscellaneous hazardous material, Technical Name Required

Incompatibilities

This chemical has weak oxidizing and reducing properties. Keep away from strong oxidizers Chromic Sulfate 837 (perchlorates, peroxides, permanganates, chlorates, nitrates, chlorine, bromine, and fluorine). When heated this chemical decomposes to chromic acid.

Waste Disposal

Return to supplier where possible. Where this is not practical, the material should be encapsulated and buried in a specially designated chemical landfill.