1-BROMO-4-FLUORO-2-NITROBENZENE
- Product Name
- 1-BROMO-4-FLUORO-2-NITROBENZENE
- CAS No.
- 446-09-3
- Chemical Name
- 1-BROMO-4-FLUORO-2-NITROBENZENE
- Synonyms
- 2-BROMO-5-FLUORONITROBENZENE;2-BroMo-5-fluo;2-Bromo-5-fluoronitribenzene;2-Bromo-5-fluoroanitrobenzene;1-Bromo-2-nitro-4-fluorobenzene;1-BROMO-4-FLUORO-2-NITROBENZENE;1-BroMo-4-Fluoro-2-nitrobenzebe;2-Bromo-5-fluoronitrobenzene98%;2-Bromo-5-fluoronitrobenzene 98%;2-BroMo-5-fluoronitrobenzene, 97+%
- CBNumber
- CB0111584
- Molecular Formula
- C6H3BrFNO2
- Formula Weight
- 220
- MOL File
- 446-09-3.mol
1-BROMO-4-FLUORO-2-NITROBENZENE Property
- Melting point:
- 37-39°C
- Boiling point:
- 148-150°C 35mm
- Density
- 1.808±0.06 g/cm3(Predicted)
- Flash point:
- 148-150°C/35mm
- storage temp.
- Sealed in dry,Room Temperature
- form
- powder to lump to clear liquid
- color
- White or Colorless to Yellow to Green
- BRN
- 2364227
- InChI
- InChI=1S/C6H3BrFNO2/c7-5-2-1-4(8)3-6(5)9(10)11/h1-3H
- InChIKey
- XRXNWKIKQFEOGO-UHFFFAOYSA-N
- SMILES
- C1(Br)=CC=C(F)C=C1[N+]([O-])=O
- CAS DataBase Reference
- 446-09-3(CAS DataBase Reference)
Safety
- Hazard Codes
- Xi
- Risk Statements
- 20/21/22-36/37/38
- Safety Statements
- 26-36/37/39-36/37
- RIDADR
- UN2811
- Hazard Note
- Irritant
- HazardClass
- 6.1
- PackingGroup
- III
- HS Code
- 29049090
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H302Harmful if swallowed
H312Harmful in contact with skin
H315Causes skin irritation
H319Causes serious eye irritation
H331Toxic if inhaled
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P405Store locked up.
N-Bromosuccinimide Price
- Product number
- B2339
- Product name
- 1-Bromo-4-fluoro-2-nitrobenzene
- Purity
- >97.0%(GC)
- Packaging
- 1g
- Price
- $25
- Updated
- 2025/07/31
- Product number
- B2339
- Product name
- 1-Bromo-4-fluoro-2-nitrobenzene
- Purity
- >97.0%(GC)
- Packaging
- 5g
- Price
- $71
- Updated
- 2025/07/31
- Product number
- B688648
- Product name
- 1-Bromo-4-fluoro-2-nitrobenzene
- Packaging
- 500mg
- Price
- $45
- Updated
- 2021/12/16
- Product number
- B688648
- Product name
- 1-Bromo-4-fluoro-2-nitrobenzene
- Packaging
- 1g
- Price
- $55
- Updated
- 2021/12/16
- Product number
- B688648
- Product name
- 1-Bromo-4-fluoro-2-nitrobenzene
- Packaging
- 2.5g
- Price
- $65
- Updated
- 2021/12/16
1-BROMO-4-FLUORO-2-NITROBENZENE Chemical Properties,Usage,Production
Chemical Properties
light yellow powder
Synthesis
394-01-4
446-09-3
General procedure for the synthesis of 2-bromo-5-fluoronitrobenzene from 2-nitro-4-fluorobenzoic acid: 6.2 mg of silver sulfate, 36.3 mg of copper acetate, 12.5 mg of 2,9-dimethyl-1,10-o-phenanthroline, 37 mg of 2-nitro-4-fluorobenzoic acid, and 30.9 mg of sodium bromide were sequentially added to a Silak reactor tube fitted with a magnetic stirrer, followed by 4 mL of dimethyl sulfoxide as solvent. The reaction mixture was heated to 160°C under an oxygen atmosphere with continuous stirring for 24 hours. Upon completion of the reaction, distilled water was added to the reaction mixture to quench the reaction, followed by extraction with ethyl acetate three times at 10 mL each. the organic phases were combined, and 21.1 mg of 2-bromo-5-fluoronitrobenzene was obtained after concentration in 48% yield.
References
[1] Journal of Organic Chemistry, 2016, vol. 81, # 7, p. 2794 - 2803
[2] Patent: CN107325002, 2017, A. Location in patent: Paragraph 0067
[3] Organic and Biomolecular Chemistry, 2018, vol. 16, # 30, p. 5416 - 5421
1-BROMO-4-FLUORO-2-NITROBENZENE Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from 1-BROMO-4-FLUORO-2-NITROBENZENE manufacturers
- Product
- 1-BROMO-4-FLUORO-2-NITROBENZENE 446-09-3
- Price
- US $0.00-0.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 20 mt
- Release date
- 2025-03-14
- Product
- 1-BROMO-4-FLUORO-2-NITROBENZENE 446-09-3
- Price
- US $0.00-0.00/KG
- Min. Order
- 1KG
- Purity
- 98.0%
- Supply Ability
- 10000KGS
- Release date
- 2025-03-13
- Product
- 1-BROMO-4-FLUORO-2-NITROBENZENE 446-09-3
- Price
- US $15.00-10.00/KG
- Min. Order
- 1KG
- Purity
- 99%+ HPLC
- Supply Ability
- Monthly supply of 1 ton
- Release date
- 2021-08-10