METHYL 2-AMINO-6-FLUORO-3-NITROBENZOATE
- Product Name
- METHYL 2-AMINO-6-FLUORO-3-NITROBENZOATE
- CAS No.
- 346691-23-4
- Chemical Name
- METHYL 2-AMINO-6-FLUORO-3-NITROBENZOATE
- Synonyms
- METHYL 2-AMINO-6-FLUORO-3-NITROBENZOATE;2-Amino-6-fluoro-3-nitro-benzoic acid methyl ester;Benzoic acid, 2-amino-6-fluoro-3-nitro-, methyl ester;2-Amino-6-fluoro-3-nitro-benzoic acid methyl ester (9CI aci)
- CBNumber
- CB01118634
- Molecular Formula
- C8H7FN2O4
- Formula Weight
- 214.15
- MOL File
- Mol file
METHYL 2-AMINO-6-FLUORO-3-NITROBENZOATE Property
- Boiling point:
- 360.9±42.0 °C(Predicted)
- Density
- 1.470±0.06 g/cm3(Predicted)
- storage temp.
- Keep in dark place,Inert atmosphere,Room temperature
- pka
- -3.91±0.25(Predicted)
- form
- crystalline solid
- color
- Yellow
Safety
- HS Code
- 2922498590
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H302Harmful if swallowed
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P301+P310IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- M332280
- Product name
- Methyl2-Amino-6-fluoro-3-nitrobenzoate
- Packaging
- 50mg
- Price
- $45
- Updated
- 2021/12/16
- Product number
- M332280
- Product name
- Methyl2-Amino-6-fluoro-3-nitrobenzoate
- Packaging
- 100mg
- Price
- $60
- Updated
- 2021/12/16
- Product number
- M332280
- Product name
- Methyl2-Amino-6-fluoro-3-nitrobenzoate
- Packaging
- 500mg
- Price
- $75
- Updated
- 2021/12/16
- Product number
- 4658-3-18
- Product name
- Methyl 2-amino-6-fluoro-3-nitrobenzoate
- Purity
- 97%
- Packaging
- 1g
- Price
- $48
- Updated
- 2021/12/16
- Product number
- 071414
- Product name
- Methyl 2-amino-6-fluoro-3-nitrobenzoate
- Purity
- 98%
- Packaging
- 1g
- Price
- $58
- Updated
- 2021/12/16
METHYL 2-AMINO-6-FLUORO-3-NITROBENZOATE Chemical Properties,Usage,Production
Synthesis
84832-01-9
346691-23-4
General procedure for the synthesis of methyl 2-amino-6-fluoro-3-nitrobenzoate from methyl 2,6-difluoro-3-nitrobenzoate: Methyl 2,6-difluoro-3-nitrobenzoate (32.55 g, 150 mmol) was dissolved in ethanol (300 mL), followed by the addition of ammonia (13 mL). The reaction mixture was stirred overnight at room temperature. Upon completion of the reaction, the resulting yellow solid product methyl 2-amino-6-fluoro-3-nitrobenzoate (18.31 g, 57% yield) was collected by filtration.
References
[1] Patent: CN104003979, 2016, B. Location in patent: Paragraph 0385; 0388; 0389
[2] Patent: CN103923088, 2016, B. Location in patent: Paragraph 0214; 0216; 0219; 01220
[3] Patent: WO2009/134850, 2009, A1. Location in patent: Page/Page column 16
[4] Bioorganic and Medicinal Chemistry Letters, 2012, vol. 22, # 7, p. 2620 - 2623
[5] Patent: US2010/305133, 2010, A1. Location in patent: Page/Page column 12
METHYL 2-AMINO-6-FLUORO-3-NITROBENZOATE Preparation Products And Raw materials
Raw materials
Preparation Products
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