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Chloromethyltrimethoxysilane

Product Name
Chloromethyltrimethoxysilane
CAS No.
5926-26-1
Chemical Name
Chloromethyltrimethoxysilane
Synonyms
ND-40;DK833;DK343;DK342;DKSI159;DKFELEX0218;Co-Formula CFS-C261;CHLOROMETHYLTRIMETHOXYSILANE;Chloromethvltrimethoxysilane;chloromethyl-trimethoxy-silan
CBNumber
CB0114833
Molecular Formula
C4H11ClO3Si
Formula Weight
170.67
MOL File
5926-26-1.mol
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Chloromethyltrimethoxysilane Property

Boiling point:
151 °C (lit.)
Density 
1.132 g/mL at 25 °C (lit.)
refractive index 
1.407 [25°C]
Flash point:
26 °F
storage temp. 
Storage temp. 2-8°C
form 
clear liquid
color 
Colorless to Almost colorless
Specific Gravity
1.125
Hydrolytic Sensitivity
7: reacts slowly with moisture/water
InChI
InChI=1S/C4H11ClO3Si/c1-6-9(4-5,7-2)8-3/h4H2,1-3H3
InChIKey
FPOSCXQHGOVVPD-UHFFFAOYSA-N
SMILES
[Si](CCl)(OC)(OC)OC
CAS DataBase Reference
5926-26-1(CAS DataBase Reference)
NIST Chemistry Reference
Silane, chloromethyl-trimethoxy-(5926-26-1)
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Safety

Hazard Codes 
F
Risk Statements 
11
Safety Statements 
16-29-33
RIDADR 
UN 1993 3/PG 2
WGK Germany 
3
RTECS 
VV2625000
TSCA 
No
HazardClass 
3
PackingGroup 
II
HS Code 
29319090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H225Highly Flammable liquid and vapour

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
597201
Product name
Chloromethyltrimethoxysilane
Purity
96%
Packaging
25g
Price
$290
Updated
2023/06/20
TCI Chemical
Product number
C3073
Product name
(Chloromethyl)trimethoxysilane
Purity
>98.0%(GC)
Packaging
5g
Price
$58
Updated
2025/07/31
TCI Chemical
Product number
C3073
Product name
(Chloromethyl)trimethoxysilane
Purity
>98.0%(GC)
Packaging
25g
Price
$173
Updated
2025/07/31
Frontier Specialty Chemicals
Product number
JK118720
Product name
Chloromethyltrimethoxysilane
Purity
96%
Packaging
5g
Price
$60
Updated
2021/12/16
AK Scientific
Product number
J99963
Product name
(Chloromethyl)trimethoxysilane
Packaging
100g
Price
$154
Updated
2021/12/16
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Chloromethyltrimethoxysilane Chemical Properties,Usage,Production

Chemical Properties

Clear transparent liquid

Uses

Chloromethyltrimethoxysilane may be used in the preparation of 1-methyl-1H-benzimidazole (MBI)-modified nanoparticles.{33} Mesoporous monolithic silica gels can also be prepared from Chloromethyltrimethoxysilane. {34}

General Description

Chloromethyltrimethoxysilane (CMTMS) is a trialkoxysilane with chloromethyl as the organofunctional group having hydrophobic characteristics. Chloromethyl is the electron withdrawing group that improves the mechanical properties of the molecule. CMTMS is mainly utilized as a silane based precursor material for the preparation of surface enhancement based coatings and other silane based products.

Synthesis

1558-25-4

149-73-5

5926-26-1

The general procedure for the synthesis of chloromethyltrimethoxysilane from chloromethyltrichlorosilane and trimethyl orthoformate was as follows: 570.2 g (3.1 mol) of chloromethyltrichlorosilane was slowly added dropwise to 1127.8 g (10.64 mol) of trimethyl orthoformate, and the dropwise acceleration was controlled so that the reaction mixture was kept at a slight boiling state. After the dropwise addition was completed, the reaction system was heated to 90°C and the reaction was maintained at this temperature for 5 hours. Upon completion of the reaction, the reaction mixture was purified by distillation, resulting in 449.8 g of the target product chloromethyltrimethoxysilane (Compound 2a). The structure of the product was confirmed by 1H NMR spectrum with the following chemical shifts δ (ppm): 2.77 (single peak, 2H, CH2), 3.58 (single peak, 9H, OCH3).

References

[1] Russian Journal of General Chemistry, 2016, vol. 86, # 8, p. 1859 - 1863
[2] Zh. Obshch. Khim., 2016, vol. 86, # 8, p. 1321 - 1326,6

Chloromethyltrimethoxysilane Preparation Products And Raw materials

Raw materials

Preparation Products

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Chloromethyltrimethoxysilane Suppliers

Lanzhou Yunlianfeng Chemical Co., LTD
Tel
0931-6521608 13831088306
Fax
0086-310-6563881
Email
dmtf@taifengchem.com
Country
China
ProdList
19
Advantage
60
Jinan Shicheng Organic Silicon Technology Co., Ltd
Tel
0531-88580030 17854171837
Fax
0531-88580030
Email
1686140776@qq.com
Country
China
ProdList
61
Advantage
58
Shanghai Aladdin Biochemical Technology Co.,Ltd.
Tel
400-6206333 13167063860
Email
anhua.mao@aladdin-e.com
Country
China
ProdList
48457
Advantage
58
J & K SCIENTIFIC LTD.
Tel
18210857532; 18210857532
Fax
86-10-82849933
Email
jkinfo@jkchemical.com
Country
China
ProdList
96815
Advantage
76
Meryer (Shanghai) Chemical Technology Co., Ltd.
Tel
021-021-61259138 18621169109
Fax
86-21-61259102
Email
market03@meryer.com
Country
China
ProdList
40228
Advantage
62
TCI (Shanghai) Development Co., Ltd.
Tel
021-67121386
Fax
021-67121385
Email
Sales-CN@TCIchemicals.com
Country
China
ProdList
24529
Advantage
81
Energy Chemical
Tel
021-021-58432009 400-005-6266
Fax
021-58436166
Email
sales8178@energy-chemical.com
Country
China
ProdList
44734
Advantage
61
Wuhan Chemwish Technology Co., Ltd
Tel
86-027-67849912
Fax
86-027-87531808
Email
sales@chemwish.com
Country
China
ProdList
35896
Advantage
56
Shanghai Sinch Parmaceuticals Tech. Co. Ltd.
Tel
+86-21-54098501
Fax
+86-21-54096319
Email
sales@sinch.com.cn
Country
China
ProdList
11598
Advantage
64
Shandong Xiya Chemical Co., Ltd
Tel
4009903999 13355009207
Fax
0539-6365991
Email
3007715519@qq.com
Country
China
ProdList
18729
Advantage
57
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View Lastest Price from Chloromethyltrimethoxysilane manufacturers

Zhuozhou Wenxi import and Export Co., Ltd
Product
Chloromethyltrimethoxysilane 5926-26-1
Price
US $15.00-10.00/KG
Min. Order
1KG
Purity
99%+ HPLC
Supply Ability
Monthly supply of 1 ton
Release date
2021-08-10
Career Henan Chemical Co
Product
Chloromethyltrimethoxysilane 5926-26-1
Price
US $2.00/KG
Min. Order
1KG
Purity
98%
Supply Ability
customise
Release date
2018-08-10

5926-26-1, ChloromethyltrimethoxysilaneRelated Search:


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