1-Bromo-2-methoxy-3-nitro-benzene
- Product Name
- 1-Bromo-2-methoxy-3-nitro-benzene
- CAS No.
- 98775-19-0
- Chemical Name
- 1-Bromo-2-methoxy-3-nitro-benzene
- Synonyms
- 2-Bromo-6-nitroanisole;3-Bromo-2-methoxynitrobenzene;1-bromo-2-methoxy-3-Nitroenzene;1-Bromo-2-methoxy-3-nitro-benzene;2-bromo-6-nitrophenyl methyl ether;Benzene,1-bromo-2-methoxy-3-nitro-;3-BroMo-2-Methoxynitrobenzene[2-BroMo-6-nitroanisole];2-BROMO-6-NITRO ANISOLE / 1-Bromo-2-methoxy-3-nitrobenzene;3-Bromo-2-methoxynitrobenzene, 1-Bromo-2-methoxy-3-nitrobenzene
- CBNumber
- CB01180356
- Molecular Formula
- C7H6BrNO3
- Formula Weight
- 232.03
- MOL File
- 98775-19-0.mol
1-Bromo-2-methoxy-3-nitro-benzene Property
- Boiling point:
- 296.4±20.0 °C(Predicted)
- Density
- 1.640±0.06 g/cm3(Predicted)
- storage temp.
- Sealed in dry,Room Temperature
- form
- solid
- color
- Off white to faint yellow
- InChI
- InChI=1S/C7H6BrNO3/c1-12-7-5(8)3-2-4-6(7)9(10)11/h2-4H,1H3
- InChIKey
- YAYBLVOBUIXMQY-UHFFFAOYSA-N
- SMILES
- C1(Br)=CC=CC([N+]([O-])=O)=C1OC
Safety
- HS Code
- 2909309090
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H302Harmful if swallowed
H315Causes skin irritation
H319Causes serious eye irritation
H332Harmful if inhaled
H335May cause respiratory irritation
- Precautionary statements
-
P280Wear protective gloves/protective clothing/eye protection/face protection.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P310Immediately call a POISON CENTER or doctor/physician.
N-Bromosuccinimide Price
- Product number
- B696760
- Product name
- 1-Bromo-2-methoxy-3-nitrobenzene
- Packaging
- 100mg
- Price
- $45
- Updated
- 2021/12/16
- Product number
- B696760
- Product name
- 1-Bromo-2-methoxy-3-nitrobenzene
- Packaging
- 10g
- Price
- $165
- Updated
- 2021/12/16
- Product number
- W9854
- Product name
- 1-Bromo-2-methoxy-3-nitrobenzene
- Packaging
- 100g
- Price
- $455
- Updated
- 2021/12/16
- Product number
- HCH0050745
- Product name
- 1-BROMO-2-METHOXY-3-NITRO-BENZENE
- Purity
- 95.00%
- Packaging
- 1G
- Price
- $708.48
- Updated
- 2021/12/16
- Product number
- HCH0050745
- Product name
- 1-BROMO-2-METHOXY-3-NITRO-BENZENE
- Purity
- 95.00%
- Packaging
- 5G
- Price
- $1274.66
- Updated
- 2021/12/16
1-Bromo-2-methoxy-3-nitro-benzene Chemical Properties,Usage,Production
Chemical Properties
White to off-white powder
Synthesis
13073-25-1
74-88-4
98775-19-0
General procedure for the synthesis of 2-bromo-6-nitroanisole from 2-bromo-6-nitrophenol (19.6 g, 90.0 mmol) and iodomethane (25.6 g, 180 mmol): first, 2-bromo-6-nitrophenol and potassium carbonate (24.9 g, 180 mmol) were mixed in acetone (400 mL). Subsequently, iodomethane was added to the mixture. The reaction mixture was heated to reflux overnight. After completion of the reaction, it was cooled to room temperature, the mixture was filtered and the filter cake was washed with ethyl acetate (100 mL). The filtrate was concentrated under reduced pressure. The residue was dissolved in ethyl acetate and the resulting solution was washed with saturated brine and dried with anhydrous sodium sulfate. Finally, the dried solution was concentrated to give 1-bromo-2-methoxy-3-nitrobenzene (20.2 g, 97% yield) as a yellow solid. The 1H-NMR spectrum (300 MHz, DMSO-d6) data of the product were as follows: δ (ppm): 3.92 (s, 3H), 7.32 (d, 1H, J = 8.1 Hz), 7.94-8.03 (m, 2H).
References
[1] Patent: EP2987787, 2016, A1. Location in patent: Paragraph 0129-0130
[2] Patent: WO2014/74661, 2014, A1. Location in patent: Paragraph 00172
[3] Patent: US2014/296229, 2014, A1. Location in patent: Paragraph 0254; 0255; 0256
[4] Patent: WO2014/154760, 2014, A1. Location in patent: Page/Page column 55
[5] Patent: EP2236500, 2010, A1. Location in patent: Page/Page column 15
1-Bromo-2-methoxy-3-nitro-benzene Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from 1-Bromo-2-methoxy-3-nitro-benzene manufacturers
- Product
- 2-Bromo-6-Nitroanisole 98775-19-0
- Price
- US $0.00-0.00/kg
- Min. Order
- 1kg
- Purity
- 99%
- Supply Ability
- 1
- Release date
- 2025-08-25
- Product
- 1-Bromo-2-methoxy-3-nitro-benzene 98775-19-0
- Price
- US $0.00-0.00/kg
- Min. Order
- 1kg
- Purity
- 98%
- Supply Ability
- 1Ton
- Release date
- 2022-09-27
- Product
- 1-Bromo-2-methoxy-3-nitro-benzene 98775-19-0
- Price
- US $101.00-1.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- g-kg-tons, free sample is available
- Release date
- 2023-12-28